TEST BANK FOR Thermodynamics Problem Solving in Physical Chemistry 1st Edition By Kathleen E. Murphy
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Exam (elaborations) TEST BANK FOR Thermodynamics Problem Solving in Physical Chemistry 1st Edition By Kathleen E. Murphy (Study Guide and Map [Full Worked Solution] (2020, CRC Press)
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---104November 20212021/2022
- 1.1 A) Calculate the values the equations have in common first: 
CH 
4 
= 25.0g 
1.00molCH 
4 
16.0g 
é 
ë 
ê 
ê 
ù 
û 
ú 
ú 
= 1.163mol V 
m 
,CH 
4 
= 
2.0L 
1.563mol 
= 1.28 
L 
mol 
Given RT = 0.08206 L-atm 
mol-K 
(303K) = 24.86 L-atm 
mol , then calculate the pressure from each equation of state: 
(a) P 
ideal 
= 
RT 
V 
m 
= 
24.86 L-atm 
mol 
1.28 L 
mol 
= 19.4atm 
(b) P 
VdW 
,CH 
4 
= 
RT 
V 
m 
- b 
- 
a 
V 
m 
2 
= 
24.86 L-atm 
mol 
(1.28 - 0.04278) L 
mol 
- 
2.283 L2-atm ...
-
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