Test Bank — Organic Chemistry, 9th Edition — John E. McMurry — ISBN 9781305080485

Organic Chemistry – 9th Edition
ST

TEST BANK
UV
IA

John E. McMurry
_A
PP

Comprehensive Test Bank for Instructors
RO

and Students
VE

© John E. McMurry
D?

All rights reserved. Reproduction or distribution without permission is prohibited.
??


©STUDYSTREAM

, TABLE OF CONTENTS
Organic Chemistry – 9th Edition
ST

John E. McMurry


1. Structure and Bonding
UV

2. Polar Covalent Bonds; Acids and Bases
3. Organic Compounds: Alkanes and Their Stereochemistry
4. Organic Compounds: Cycloalkanes and Their Stereochemistry
5. Stereochemistry at Tetrahedral Centers
6. An Overview of Organic Reactions
IA

7. Alkenes: Structure and Reactivity
8. Alkenes: Reactions and Synthesis
9. Alkynes: An Introduction to Organic Synthesis
_A

10. Organohalides
11. Reactions of Alkyl Halides: Nucleophilic Substitutions and Eliminations
12. Structure Determination: Mass Spectrometry and Infrared Spectroscopy
13. Structure Determination: Nuclear Magnetic Resonance Spectroscopy
PP
14. Conjugated Compounds and Ultraviolet Spectroscopy
15. Benzene and Aromaticity
16. Chemistry of Benzene: Electrophilic Aromatic Substitution
17. Alcohols and Phenols
18. Ethers and Epoxides; Thiols and Sulfides
RO

19. Aldehydes and Ketones: Nucleophilic Addition Reactions
20. Carboxylic Acids and Nitriles
21. Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
22. Carbonyl Alpha-Substitution Reactions
23. Carbonyl Condensation Reactions
VE

24. Amines and Heterocycles
25. Biomolecules: Carbohydrates
26. Biomolecules: Amino Acids, Peptides, and Proteins
27. Biomolecules: Lipids
D?

28. Biomolecules: Nucleic Acids
29. The Organic Chemistry of Metabolic Pathways
30. Orbitals and Organic Chemistry: Pericyclic Reactions
31. Synthetic Polymers
??

, Chapter 01 - Structure and Bonding
1. Give the ground-state electron configuration for carbon (atomic number 6).
ANSWER: 1s22s22px12py1 or 1s22s22p2
POINTS: 1
ST
2. Give the ground-state electron configuration for fluorine (atomic number 9).
ANSWER: 1s22s22px2 2py2 2pz 1 or 1s22s22p5
POINTS: 1
UV
3. Give the ground-state electron configuration for magnesium (atomic number 12).
ANSWER: 1s22s22p63s2
POINTS: 1

4. How many electrons does silicon have in its valence shell?
IA
ANSWER: four
POINTS: 1

Exhibit 1-1
_A
Write valid Lewis (electron-dot) structures for each formula below. Show all electrons as dots and show all non-bonding
electrons.

5. C2Cl4 tetrachloroethylene
ANSWER:
PP
POINTS: 1

6. CO2 carbon dioxide
RO
ANSWER:
POINTS: 1

7. CH4O methanol
ANSWER:
VE

POINTS: 1
D?
Exhibit 1-2
Consider the structure of urea, shown below, to answer the following question(s).
??
8. Refer to Exhibit 1-2. Fill in any non-bonding valence electrons that are missing from the line-bond structure.



Cengage Learning Testing, Powered by Cognero Page 1

, Chapter 01 - Structure and Bonding
ANSWER:


POINTS: 1
ST
9. Refer to Exhibit 1-2. The carbon atom in urea is:

a. sp3 hybridized
b. sp2 hybridized
UV
c. sp hybridized
d. not hybridized
ANSWER: b
POINTS: 1
IA
10. Refer to Exhibit 1-2. The predicted NH2−C=O bond angle in urea is:

a. 109.5°
b. 120°
c. 180°
_A
d. not predictable
ANSWER: b
POINTS: 1

Exhibit 1-3
PP
Determine the hybridization for the indicated atoms in each structure below.
RO

11. Refer to Exhibit 1-3. The hybridization of this oxygen atom (A) is .
ANSWER: sp2
POINTS: 1
VE
12. Refer to Exhibit 1-3. The hybridization of this oxygen atom (B) is .
ANSWER: sp3
POINTS: 1
D?
13. Refer to Exhibit 1-3. The hybridization of this carbon atom (C) is .
ANSWER: sp3
POINTS: 1
??
14. Refer to Exhibit 1-3. The hybridization of this carbon atom (D) is .
ANSWER: sp
POINTS: 1


Cengage Learning Testing, Powered by Cognero Page 2