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OCR A LEVEL CHEMISTRY analytical teqniques ALL QUESTIONS

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OCR A LEVEL CHEMISTRY analytical teqniques ALL QUESTIONS

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1 Analysis of an unknown organic compound J produces the following results.


Elemental analysis by mass of compound J


C, 80.60%; H, 7.46%; O, 11.94%
Mass spectrum of compound J




IR spectrum of compound J




Proton NMR spectrum of compound J




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, The numbers by the peaks are the relative peak areas.


Determine the structure of compound J, showing all your reasoning.




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, [6]


2 Which statement gives a valid scientific reason for global warming?


A Infrared radiation causes bonds in CH4 molecules to vibrate more.
B Infrared radiation causes O2 molecules to vibrate more.
C Ultraviolet radiation causes bonds in CO2 to vibrate more.
D Ultraviolet radiation causes bonds in CFC molecules to break.



Your answer [1]



3 Which compound could have produced the IR spectrum shown below?




A HOCH2CHO
B CH3CH2COOH
C CH3CH2COOCH3
D (CH3)2C(OH)COOH



Your answer [1]




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, 4 Which statement about infrared radiation (IR) is not correct?


A Absorption of IR by molecules such as CO2, H2O and CH4 has been linked to global warming.
B IR causes CFC molecules to produce chlorine radicals that initiate ozone breakdown in the upper
atmosphere.
C IR causes some covalent bonds to vibrate more and absorb energy.
D IR is used in modern breathalysers to detect ethanol.



Your answer [1]



5 An alcohol CH3CH2CH(CH3)OH produces a mass spectrum.


The mass spectrum contains a large fragment ion at m/z = 45.


What is the possible identity of this fragment ion?


A CH2CHOH+
B CH2CH2OH+
C CH3CHOH+
D CH3CH2CH+



Your answer [1]




6 Compound X is an organic compound with two functional groups.


Compound X has the percentage composition by mass:
C, 40.91%; H, 4.54%; O, 54.55%.


Compound X does not decolourise bromine water.


A scientist analyses compound X using mass spectrometry and infrared spectroscopy.




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