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Exam (elaborations)

Instrumental Analysis – Exam 1 Questions with Verified Answers – Fundamentals, Spectroscopy, and Analytical Methodology

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This document provides a verified and comprehensive set of questions and answers for Exam 1 in Instrumental Analysis. It covers core topics including error types (systematic, random, absolute), analytical steps, IR and UV-Vis spectroscopy principles, instrumental components (sources, detectors, filters), and concepts such as Beer's Law, diffraction, sensitivity, selectivity, and resolution. Additional emphasis is placed on noise sources (thermal, shot, flicker), molecular interactions, and comparison of qualitative vs. quantitative methods. This is an ideal foundational resource for analytical chemistry students.

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Institution
Instrumental Analysis
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Instrumental Analysis

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Uploaded on
June 6, 2025
Number of pages
9
Written in
2024/2025
Type
Exam (elaborations)
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Questions & answers

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Instrumental Analysis Exam 1 questions with
verified answers
absolute error Ans✓✓✓ = abs(true value - measured value) (accuracy)


accuracy Ans✓✓✓ how close a measured analytical result is to the true
answer.


Analyte Ans✓✓✓ substance to be measured


Apperance of water in IR Ans✓✓✓ Symmetric stretching at 4000 cm-1
and scissoring from 2000-1300 cm-1.


Atomic Spectra Ans✓✓✓ little to no noise. simple and basic. nothing in
terms of levels


Beer's Law Ans✓✓✓ Absorbance = Adsoptivity * path length *
concentration (additive).


Bending Ans✓✓✓ Change in bond angle. Scissoring, Wagging, Rocking,
and Twisting.


Bolometer Ans✓✓✓ Measure temperature as a function of a change in
resistance between two materials.

, Chemical Noise Ans✓✓✓ noise caused by chemical interactions
(humidty and chemical fumes)


determinate error Ans✓✓✓ cahttp://quizlet.com/9756801/edit/n be
determined and corrected (human error, instrumental error)


determinate error Ans✓✓✓ how far from the correct answer (human,
instrument, method error).


Diffraction Ans✓✓✓ beam of radiaiton is bent as it passes a "sharp"
barrier or "narrow" opening.


Diffraction Grating Ans✓✓✓ Parallel lines that diffracts the light. High
order diffraction has different wavelengths at same angle so more
filters needed.


Dipole Moment Ans✓✓✓ Polar molecules that produce ir activity


Double-Beam UV-VIS Ans✓✓✓ Sample and Blank at same time.
Problem with alignment of mirrors to the detector.


Environmental Noise Ans✓✓✓ Noise from the outside world power
lines, radio waves, power fluctuations.

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