TEST BANK for Organic Chemistry 6th Edition
m m m m m m
Smith / All Chapters 1 - 29 / Full Complete
m m m m m m m m m m
Page 1
m
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
m m m m m m
Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
m m m
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
m m m m m m m m
Substitution
m
Chapter 21
m Substitution Reactions of Carbonyl Compounds at the α-Carbon
m m m m m m m m
Chapter 22
m Carbonyl Condensation Reactions
m m m
Chapter 23
m Amines
m
Chapter 24
m Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
m m m m m m
Chapter 25
m Pericyclic Reactions
m m
Chapter 26
m Carbohydrates
m
Chapter 27
m Amino Acids and Proteins
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Chapter 28
m Synthetic Polymers
m m
Chapter 29
m Lipids (Available online)
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Page 2 m
, Chapter 1: Structure and Bonding m m m m
1. What is the ground-state electronic configuration of a carbon
m m m m m m m m
atom? A) 1s2, 2s2, 2p5
m m m B) 1s2, 2s2, 2p2 C) 1s2, 2s2,
m m m m m m m
2p6
m D) 1s2, 2s2, 2p4 m m m
2. What is the ground-state electronic configuration of a fluorine
m m m m m m m m
atom?A) 1s2, 2s2, 2p2
m m m B) 1s2, 2s2, 2p3 C) 1s2, 2s2,
m m m m m m m
4 2 2 5
2p
m D) 1s , 2s , 2p m m m
3. What is the ground-state electronic configuration of a magnesium cation
m m m m m m m m m
(Mg2+)?A)
m m 1s2, 2s2, 2p6 C) 1s2, 2s2, m m m
6 2
2p , 3s
m m
B) 1s2, 2s2, 2p6, 3s1
m m m D) 1s2, 2s2, 2p6, 3s2, 3p2
m m m m
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
m m m m m m m m m m
)?A) 1s2, 2s2, 2p6
m m m C) 1s2, 2s2, 2p6, 3s2, 3p5 m m m m
B) 1s2, 2s2, 2p6, 3s2, 3p6
m m m m D) 1s2, 2s2, 2p6, 3s2, 3p4
m m m m
5. Which of the following statements about valence electrons is true?
m m m m m m m m m
A) They are the most tightly held electrons.
m m m m m m
B) They do not participate in chemical reactions.
m m m m m m
Page 3
m
, Chapter 1: Structure and m m m
Bonding
m
C) They are the outermost electrons.
m m m m
D) They reveal the period number of a second-row element.
m m m m m m m m
6. Which of the following statements about bonding is true?
m m m m m m m m
A) Covalent bonds result from the transfer of electrons from one element to another.
m m m m m m m m m m m m
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
m m m m m m m m m m m m m
C) Ionic bonds result from the sharing of electrons between two non-metals.
m m m m m m m m m m
D) Covalent bonds result from the sharing of electrons between two metals.
m m m m m m m m m m
7. Which of the following would you expect to have ionic bonds?
m m m m m m m m m m
A) CO B) FBr C) NF3 D) NaCl m m m
8. Which of the following molecules has nonpolar covalent bonds?
m m m m m m m m
A) HCl B) N2 C) CHCl3 D) NO m m m
9. Which of the following molecules contain both covalent and ionic bonds?
m m m m m m m m m m
A) I, II B) I, IV C) II, III D) II, IV
m m m m m m m
10. Arrange the following bonds in decreasing order of ionic character, putting the
m m m m m m m m m m m
mostionic first.
m m m
A) I > II > III > IV
m m m m m m C) IV > III > II > I m m m m m m
B) IV > II > I > III
m m m m m m D) IV > II > III > I m m m m m m
11. Which of the following statements correctly describes the typical number of bonds
m m m m m m m m m m m
forcarbon, nitrogen, and oxygen in most neutral organic molecules?
m m m m m m m m m m
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
m m m m m m m m m m m
forms3 covalent bonds.
m m m m
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
m m m m m m m m m m m
forms2 covalent bonds.
m m m m
Page 4 m
m m m m m m
Smith / All Chapters 1 - 29 / Full Complete
m m m m m m m m m m
Page 1
m
,Chapter 1 Structure and Bonding
m m m m
Chapter 2 Acids and Bases
m m m m
Chapter 3 Introduction to Organic Molecules and Functional Groups
m m m m m m m m
Chapter 4 Alkanes
m m
Chapter 5 Stereochemistry
m m
Chapter 6 Understanding Organic Reactions
m m m m
Chapter 7 Alkyl Halides and Nucleophilic Substitution
m m m m m m
Chapter 8 Alkyl Halides and Elimination Reactions
m m m m m m
Chapter 9 Alcohols, Ethers, and Related Compounds
m m m m m m
Chapter 10 Alkenes and Addition Reactions
m m m m m
Chapter 11 Alkynes and Synthesis
m m m m
Chapter 12 Oxidation and Reduction
m m m m
Spectroscopy A Mass Spectrometry
m m m
Spectroscopy B Infrared Spectroscopy
m m m
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
m m m m m
Chapter 13 Radical Reactions
m m m
Chapter 14 Conjugation, Resonance, and Dienes
m m m m m
Chapter 15 Benzene and Aromatic Compounds
m m m m m
Chapter 16 Reactions of Aromatic Compounds
m m m m m
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
m m m m m m m
Oxidation and Reduction
m m m
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
m m m m m
Chapter 19 Carboxylic Acids and Nitriles
m m m m m
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
m m m m m m m m
Substitution
m
Chapter 21
m Substitution Reactions of Carbonyl Compounds at the α-Carbon
m m m m m m m m
Chapter 22
m Carbonyl Condensation Reactions
m m m
Chapter 23
m Amines
m
Chapter 24
m Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
m m m m m m
Chapter 25
m Pericyclic Reactions
m m
Chapter 26
m Carbohydrates
m
Chapter 27
m Amino Acids and Proteins
m m m m
Chapter 28
m Synthetic Polymers
m m
Chapter 29
m Lipids (Available online)
m m m
Page 2 m
, Chapter 1: Structure and Bonding m m m m
1. What is the ground-state electronic configuration of a carbon
m m m m m m m m
atom? A) 1s2, 2s2, 2p5
m m m B) 1s2, 2s2, 2p2 C) 1s2, 2s2,
m m m m m m m
2p6
m D) 1s2, 2s2, 2p4 m m m
2. What is the ground-state electronic configuration of a fluorine
m m m m m m m m
atom?A) 1s2, 2s2, 2p2
m m m B) 1s2, 2s2, 2p3 C) 1s2, 2s2,
m m m m m m m
4 2 2 5
2p
m D) 1s , 2s , 2p m m m
3. What is the ground-state electronic configuration of a magnesium cation
m m m m m m m m m
(Mg2+)?A)
m m 1s2, 2s2, 2p6 C) 1s2, 2s2, m m m
6 2
2p , 3s
m m
B) 1s2, 2s2, 2p6, 3s1
m m m D) 1s2, 2s2, 2p6, 3s2, 3p2
m m m m
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
m m m m m m m m m m
)?A) 1s2, 2s2, 2p6
m m m C) 1s2, 2s2, 2p6, 3s2, 3p5 m m m m
B) 1s2, 2s2, 2p6, 3s2, 3p6
m m m m D) 1s2, 2s2, 2p6, 3s2, 3p4
m m m m
5. Which of the following statements about valence electrons is true?
m m m m m m m m m
A) They are the most tightly held electrons.
m m m m m m
B) They do not participate in chemical reactions.
m m m m m m
Page 3
m
, Chapter 1: Structure and m m m
Bonding
m
C) They are the outermost electrons.
m m m m
D) They reveal the period number of a second-row element.
m m m m m m m m
6. Which of the following statements about bonding is true?
m m m m m m m m
A) Covalent bonds result from the transfer of electrons from one element to another.
m m m m m m m m m m m m
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
m m m m m m m m m m m m m
C) Ionic bonds result from the sharing of electrons between two non-metals.
m m m m m m m m m m
D) Covalent bonds result from the sharing of electrons between two metals.
m m m m m m m m m m
7. Which of the following would you expect to have ionic bonds?
m m m m m m m m m m
A) CO B) FBr C) NF3 D) NaCl m m m
8. Which of the following molecules has nonpolar covalent bonds?
m m m m m m m m
A) HCl B) N2 C) CHCl3 D) NO m m m
9. Which of the following molecules contain both covalent and ionic bonds?
m m m m m m m m m m
A) I, II B) I, IV C) II, III D) II, IV
m m m m m m m
10. Arrange the following bonds in decreasing order of ionic character, putting the
m m m m m m m m m m m
mostionic first.
m m m
A) I > II > III > IV
m m m m m m C) IV > III > II > I m m m m m m
B) IV > II > I > III
m m m m m m D) IV > II > III > I m m m m m m
11. Which of the following statements correctly describes the typical number of bonds
m m m m m m m m m m m
forcarbon, nitrogen, and oxygen in most neutral organic molecules?
m m m m m m m m m m
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
m m m m m m m m m m m
forms3 covalent bonds.
m m m m
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
m m m m m m m m m m m
forms2 covalent bonds.
m m m m
Page 4 m
