solute-solute - ✔️✔️(usually changeHsolute-solute =+ (endothermic)
-bc the energy must be absorbed to break up inter molecular forces between solute
molecules
solute-solvent - ✔️✔️(usually changeHsolute-solvent = - (exothermic)
-bc the solvent molecules cluster around solute particles, forming inter molecular forces
molartiy - ✔️✔️moles/liters
molality - ✔️✔️moles/kg
percent mass - ✔️✔️mass component/total mass of solution *
enthalpy (H) is negative - ✔️✔️exothermic--flows from the system into the surroundings
enthalpy (H) is positive - ✔️✔️endothermic-- flows from the surroundings into the
system
entropy (S) is negative - ✔️✔️randomness of the system decreases
entropy (S) is positive - ✔️✔️randomness of the system increases
entropy: state function or nah? - ✔️✔️entropy is a state function (Change in S=
S(final)-S(initial)
temperature (entropy) - ✔️✔️as temperature increases the random molecular motion
increases --> kinetic energy of molecules increase --. therefore entropy increases
1st law of Thermodyamics - ✔️✔️-in any process, spontaneous or non spontaneous,
the total energy of a system & its surroundings is constant
2nd law of Thermodynamics - ✔️✔️-the principle that the total entropy of the universe
increases in any spontaneous process
-changeSuniverse=changeSsys+changeSsurr
changSuniverse (signs) - ✔️✔️S>0 = spontaneous
S<0 = non spontaneous
S=0 = rxn at equilibrium