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Chemistry class 12th Transition_Elements_Properties

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Transition elements exhibit unique properties due to their partially filled d-orbitals. They have high melting and boiling points, high density, and are good conductors of heat and electricity due to strong metallic bonding. They show multiple oxidation states because of the similar energy levels of 3d and 4s electrons. Many transition metals form colored compounds due to d-d electron transitions. They exhibit paramagnetism due to unpaired electrons. They also act as catalysts in chemical reactions by providing alternative reaction pathways. Their hardness, malleability, and tensile strength make them essential in industries like construction, electronics, and manufacturing.

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General Properties of Transition Elements (d-Block)




Transition elements (d-block elements) are the elements found in groups 3 to 12 of the periodic

table.

They exhibit unique properties due to their partially filled d-orbitals.



1. **Electronic Configuration**

- Transition metals have an electronic configuration of (n-1)d^1-10 ns^1-2.

- This leads to variable oxidation states and complex chemical behavior.



2. **Variable Oxidation States**

- Unlike s-block elements, transition metals show multiple oxidation states.

- Example: Fe can exist as Fe^2+ and Fe^3+, Mn can exist as Mn^2+, Mn^3+, Mn4+, Mn5+,

Mn6+, Mn7+.



3. **Formation of Colored Compounds**

- d-d electron transitions absorb visible light, giving transition metal compounds vibrant colors.

- Example: Cu^2+ appears blue, Cr^3+ appears green.



4. **Catalytic Properties**

- Many transition metals and their compounds act as catalysts due to their ability to change

oxidation states.

- Example: Fe in the Haber process, V2O5 in the Contact process.



5. **Complex Formation**

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Publisher: 2019 ISBN: 9789351764649 Edition: Unknown

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