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Chemistry class 12th Complex_Reactions_Explanation

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Complex reactions involve multiple steps, consisting of two or more elementary reactions that occur sequentially or in parallel. These reactions often include intermediates, catalysts, and transition states, making their kinetics more intricate than simple reactions. They can be classified as consecutive, parallel, or chain reactions. The overall rate law is determined by the slowest step, known as the rate-determining step. Complex reactions play a crucial role in biochemical pathways, industrial synthesis, and combustion processes. Understanding their mechanisms helps in optimizing reaction conditions, improving yields, and designing efficient catalysts for various chemical and pharmaceutical applications.

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Complex Reactions: Full Explanation




1. What Are Complex Reactions?

A complex reaction is a chemical reaction that occurs through multiple intermediate steps rather

than a single step.

Each step is called an elementary reaction, and the overall reaction is the sum of these steps.



Key Characteristics of Complex Reactions:

- Involve multiple steps (reaction mechanism).

- Include reaction intermediates (temporary species formed during the reaction).

- Have a rate law that is not directly derived from the balanced equation.

- May exhibit different reaction orders based on the mechanism.



2. Types of Complex Reactions



(A) Consecutive Reactions (Stepwise or Sequential Reactions)

These reactions occur in multiple steps where the product of one step becomes the reactant of the

next.



Example: Decomposition of Nitrogen Dioxide (NO2)

NO2 -> NO + O

O + O2 -> O3

Here, O (oxygen atom) is an intermediate.



(B) Parallel (Simultaneous) Reactions

A single reactant forms multiple products through different reaction pathways.
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