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Chemistry class 12th Electrochemistry_Introduction

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Electrochemistry is the study of chemical processes that involve the movement of electrons, leading to the conversion of chemical energy into electrical energy and vice versa. It focuses on redox reactions, where oxidation (loss of electrons) and reduction (gain of electrons) occur simultaneously. Key concepts include electrochemical cells, such as galvanic (voltaic) cells that generate electricity and electrolytic cells that use electricity to drive reactions. Standard electrode potential, the Nernst equation, conductivity, and corrosion are also covered. Applications include batteries, fuel cells, and electrolysis processes like metal refining and electroplating, making electrochemistry essential in industrial and technological advancements.

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Introduction to Electrochemistry


Electrochemistry is the branch of chemistry that studies the
relationship between electricity and chemical
reactions. It involves the study of redox (oxidation-reduction)
reactions where electrons are transferred between
species.


Key Concepts:


1. Oxidation and Reduction:
- Oxidation: Loss of electrons.
- Reduction: Gain of electrons.
- These processes occur simultaneously in a redox reaction.


2. Electrochemical Cells: Devices that convert chemical energy into
electrical energy or vice versa.
- Galvanic (Voltaic) Cells: Generate electrical energy from
spontaneous redox reactions (e.g., batteries).
- Electrolytic Cells: Use electrical energy to drive non-spontaneous
chemical reactions (e.g., electrolysis).


3. Electrode Types:
- Anode: The electrode where oxidation occurs.
- Cathode: The electrode where reduction occurs.


4. Cell Potential (Electromotive Force, EMF): A measure of the driving
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