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Chemistry class 12th KCl_Conductivity_Table

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Potassium chloride (KCl) is commonly used as a standard in conductivity measurements due to its stable and well-known conductivity values. The KCl conductivity table provides the specific conductivity () of KCl solutions at different concentrations and temperatures. Conductivity increases with concentration but reaches a limit due to ion pairing. Temperature also affects conductivity, as higher temperatures enhance ion mobility. Standard KCl solutions (e.g., 0.01 M, 0.1 M) are used to calibrate conductivity meters. These tables help in accurate electrochemical measurements, water quality testing, and industrial applications requiring precise conductivity standards.

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Conductivity and Molar Conductivity of KCl Solutions at 298.15K


This table presents the conductivity (k) and molar conductivity (Lambda_m) of potassium chloride
(KCl) solutions at 298.15 K (25°C).


Concentration (mol/L) Conductivity (S/m) Molar Conductivity (S·m²/mol)

0.0001 1.41 x 10^-3 141.0

0.001 1.29 x 10^-2 129.0

0.005 5.92 x 10^-2 118.4

0.01 1.11 x 10^-1 111.0

0.05 4.82 x 10^-1 96.4

0.1 8.53 x 10^-1 85.3

0.2 1.38 69.0

0.5 2.76 55.2

1.0 3.92 39.2


Notes:

- Conductivity (k) decreases with dilution due to fewer charge carriers.
- Molar conductivity (Lambda_m) increases with dilution as ion interactions decrease.
- The limiting molar conductivity (Lambda_m0) of KCl at infinite dilution is 149.86 S·m²/mol.
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