TEST BANK for Organic Chemistry 6th Edition Smith / All Chapters 1 - 29 / Full Complete

Chapter 1 Structure and Bonding Chapter 2 Acids and Bases Chapter 3 Introduction to Organic Molecules and Functional Groups Chapter 4 Alkanes Chapter 5 Stereochemistry Chapter 6 Understanding Organic Reactions Chapter 7 Alkyl Halides and Nucleophilic Substitution Chapter 8 Alkyl Halides and Elimination Reactions Chapter 9 Alcohols, Ethers, and Related Compounds Chapter 10 Alkenes and Addition Reactions Chapter 11 Alkynes and Synthesis Chapter 12 Oxidation and Reduction Spectroscopy A Mass Spectrometry Spectroscopy B Infrared Spectroscopy Spectroscopy C Nuclear Magnetic Resonance Spectroscopy Chapter 13 Radical Reactions Chapter 14 Conjugation, Resonance, and Dienes Chapter 15 Benzene and Aromatic Compounds Chapter 16 Reactions of Aromatic Compounds Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxidation and Reduction Chapter 18 Aldehydes and Ketones—Nucleophilic Addition Chapter 19 Carboxylic Acids and Nitriles Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon Chapter 22 Carbonyl Condensation Reactions Chapter 23 Amines Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis Chapter 25 Pericyclic Reactions Chapter 26 Carbohydrates Chapter 27 Amino Acids and Proteins Chapter 28 Synthetic Polymers Chapter 29 Lipids (Available online) Page 3 Chapter 1: Structure and Bonding 1. What is the ground-state electronic configuration of a carbon atom? A) 1s2 , 2s2 , 2p5 B) 1s2 , 2s2 , 2p2 C) 1s2 , 2s2 , 2p6 D) 1s2 , 2s2 , 2p4 2. What is the ground-state electronic configuration of a fluorine atom? A) 1s2 , 2s2 , 2p2 B) 1s2 , 2s2 , 2p3 C) 1s2 , 2s2 , 2p4 D) 1s2 , 2s2 , 2p5 3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)? A) 1s2 , 2s2 , 2p6 C) 1s2 , 2s2 , 2p6 , 3s2 B) 1s2 , 2s2 , 2p6 , 3s1 D) 1s2 , 2s2 , 2p6 , 3s2 , 3p2 4. What is the ground-state electronic configuration of a chlorine anion (Cl—)? A) 1s2 , 2s2 , 2p6 C) 1s2 , 2s2 , 2p6 , 3s2 , 3p5 B) 1s2 , 2s2 , 2p6 , 3s2 , 3p6 D) 1s2 , 2s2 , 2p6 , 3s2 , 3p4 5. Which of the following statements about valence electrons is true? A) They are the most tightly held electrons. B) They do not participate in chemical reactions. Chapter 1: Structure and Bonding Page 4 C) They are the outermost electrons. D) They reveal the period number of a second-row element. 6. Which of the following statements about bonding is true? A) Covalent bonds result from the transfer of electrons from one element to another. B) Ionic bonds result from the transfer of electrons from a metal to a non-metal. C) Ionic bonds result from the sharing of electrons between two non-metals. D) Covalent bonds result from the sharing of electrons between two metals. 7. Which of the following would you expect to have ionic bonds? A) CO B) FBr C) NF3 D) NaCl 8. Which of the following molecules has nonpolar covalent bonds? A) HCl B) N2 C) CHCl3 D) NO 9. Which of the following molecules contain both covalent and ionic bonds? A) I, II B) I, IV C) II, III D) II, IV 10. Arrange the following bonds in decreasing order of ionic character, putting the most ionic first. A) I > II > III > IV C) IV > III > II > I B) IV > II > I > III D) IV > II > III > I 11. Which of the following statements correctly describes the typical number of bonds for carbon, nitrogen, and oxygen in most neutral organic molecules? A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms 3 covalent bonds. B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms 2 covalent bonds. Chapter 1: Structure and Bonding Page 5 C) Carbon forms 4 covalent bonds, nitrogen forms 5 covalent bonds and oxygen forms 2 covalent bonds. D) Carbon forms 4 covalent bonds, nitrogen forms 5 covalent bonds and oxygen forms 4 covalent bonds. 12. Which is not an acceptable Lewis structure for the anion CH2NCO—? A) I B) II C) III D) IV 13. Which of the following Lewis structures is correct? A) I B) II C) III D) IV 14. Which of the following Lewis structures is correct? A) I, II B) I, III C) II, III D) III, IV 15. Which is the correct Lewis structure for acetic acid (CH3CO2H)? A) I B) II C) III D) IV Chapter 1: Structure and Bonding Page 6 16. In which of the following ions does carbon have a formal charge? A) I B) II C) III D) None of the above 17. In which of the following ions does carbon have a formal charge? A) I B) II C) III D) None of the above 18. What is the formal charge of carbon in carbon monoxide (CO) when drawn with a triple bond? A) 0 B) -2 C) -1 D) +1 19. Which of the following statements about constitutional isomers is true? A) Constitutional isomers are different molecules having different molecular formula. B) Constitutional isomers are different molecules having same molecular formula. C) Constitutional isomers are same molecules having different molecular formula. D) Constitutional isomers are same molecules having the same molecular formula. 20. How many constitutional isomers are there for a molecule having the molecular formula C2H6O? A) 1 B) 2 C) 3 D) 4 21. How many constitutional isomers are there for a molecule having the molecular C3H8O? A) 1 B) 2 C) 3 D) 4 22. How many constitutional isomers are there for a molecule having the molecular formula C3H6? A) 1 B) 2 C) 3 D) 4 23. How many constitutional isomers are there for a molecule having the molecular formula C2H4Cl2? A) 1 B) 2 C) 3 D) 4 24. How many different isomers are there for a compound having the molecular formula C3H6O? A) 4 B) 5 C) 6 D) 7