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Chemistry class 12th Classification_Metals_Conductors_Semiconductors

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Materials are classified into metals, semiconductors, and insulators based on their electrical conductivity and band structure. Metals (e.g., copper, silver) have high conductivity due to free electrons in their overlapping valence and conduction bands. Insulators (e.g., rubber, glass) have a wide band gap, preventing electron flow. Semiconductors (e.g., silicon, germanium) have a moderate band gap, allowing controlled conductivity, which increases with temperature or doping. Semiconductors are further classified as intrinsic (pure) or extrinsic (doped with impurities). This classification is fundamental in electronics, where semiconductors are used in diodes, transistors, and integrated circuits, powering modern technology.

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Classification of Metals, Conductors, and Semiconductors




Classification of Metals, Conductors, and Semiconductors


1. Introduction
Materials are classified based on their electrical conductivity into three main categories:
- Metals (Conductors)
- Semiconductors
- Insulators


The ability of a material to conduct electricity depends on the availability of free electrons and the
band structure of the material.


2. Conductors (Metals)
Definition:
Conductors are materials that allow electric current to pass through them easily due to the presence
of free electrons.


Properties of Conductors:
1. High Electrical Conductivity - They have very low electrical resistance.
2. Large Number of Free Electrons - The conduction band is partially filled or overlaps with the
valence band.
3. Low Resistivity (rho) - In the range of 10^-8 to 10^-6 Ohmm.
4. Ohm's Law Obedience - They follow Ohm's Law: V = IR.
5. Temperature Effect - Their resistance increases with temperature.
6. Examples - Copper, Silver, Gold, Aluminum, Iron.


Why Do Metals Conduct Electricity?
In metals, the valence band and conduction band overlap, allowing electrons to move freely, making
them excellent conductors.


3. Semiconductors
Definition:
Semiconductors are materials whose electrical conductivity lies between conductors and insulators.
Their conductivity can be controlled by external factors like temperature and doping.
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