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STRUCTURE AND BONDING IN ORGANIC MOLECULES NOTES

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This document is meant to help you study the topic on structure and bonding in organic molecules and examples gives in each subtopics. It also has a summary of each sub topic which will make it easy for you to understand.

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February 8, 2025
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2017/2018
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Structure and bonding

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Scope of Organic Chemistry

Organic chemistry is a vast and diverse branch of chemistry that focuses on the structure,
properties, composition, reactions, and synthesis of carbon-containing compounds. The scope of
organic chemistry extends across various scientific and industrial fields, making it one of the
most important disciplines in chemistry.



1. Definition and Importance

Organic chemistry is the study of compounds primarily composed of carbon and hydrogen, often
containing other elements such as oxygen, nitrogen, sulfur, phosphorus, and halogens. These
compounds form the basis of life and many materials used in daily life.



2. Classification of Organic Compounds

Organic compounds are classified based on their functional groups and structure, including:

 Alkanes, Alkenes, and Alkynes (Hydrocarbons)
 Aromatic Compounds (Benzene and derivatives)
 Alcohols, Phenols, and Ethers
 Aldehydes and Ketones
 Carboxylic Acids and Derivatives (Esters, Amides, Anhydrides)
 Nitrogen-containing Compounds (Amines, Nitriles)
 Polymers and Macromolecules (Proteins, DNA, Plastics)



3. Scope in Different Fields

A. Biological Sciences

 Biochemistry: Study of biomolecules like proteins, carbohydrates, lipids, and nucleic
acids.
 Pharmacology: Development of drugs and medicines.
 Genetics and Molecular Biology: DNA, RNA, and genetic engineering.

B. Industrial and Technological Applications

 Pharmaceutical Industry: Drug discovery, synthesis, and formulation.
 Petroleum and Petrochemicals: Fuels, lubricants, and synthetic materials.
 Plastics and Polymers: Development of synthetic materials like nylon, polyethylene, and
polyesters.

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,  Dyes and Pigments: Used in textiles, food, and cosmetics.
 Agrochemicals: Fertilizers, pesticides, and herbicides.

C. Environmental Chemistry

 Green Chemistry: Development of eco-friendly and sustainable chemical processes.
 Pollution Control: Study of organic pollutants and their degradation.

D. Material Science and Nanotechnology

 Advanced Materials: Organic semiconductors, nanomaterials, and biomaterials.
 Organic Electronics: Development of OLEDs, conducting polymers, and flexible
electronics.



4. Organic Chemistry in Everyday Life

Organic chemistry is present in various everyday materials and products:

 Food Chemistry: Fats, proteins, carbohydrates, vitamins, and food preservatives.
 Cosmetics: Lotions, perfumes, and hair care products.
 Household Products: Detergents, soaps, and cleaning agents.



5. Research and Future Prospects

 Medicinal Chemistry: New drug synthesis and targeted therapies.
 Sustainable Energy: Biofuels, fuel cells, and organic solar cells.
 Artificial Intelligence in Organic Synthesis: Automation of chemical reactions.


Coulomb Forces: A Simplified View of
Bonding
Introduction
Coulomb forces are the fundamental electrostatic interactions between charged particles. In
chemistry, they play a crucial role in bonding by governing the attractions and repulsions
between atoms, ions, and molecules. This concept is essential to understanding different types of
chemical bonds, including ionic, covalent, and intermolecular forces.




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,1. Coulomb’s Law: The Basis of Electrostatic Forces
Coulomb’s law mathematically describes the force between two charged particles:

F=kq1q2r2F = k \frac{q_1 q_2}{r^2}

Where:

 FF is the force between the charges,
 kk is Coulomb’s constant (8.99×1098.99 \times 10^9 N·m²/C²),
 q1q_1 and q2q_2 are the magnitudes of the charges,
 rr is the distance between the charges.

Key Insights from Coulomb’s Law

 Attractive forces occur when charges are opposite (e.g., positive and negative).
 Repulsive forces occur when charges are like (e.g., positive-positive or negative-
negative).
 Force strength increases when charges are larger or closer together.




2. Coulomb Forces in Chemical Bonding
Coulomb interactions play a fundamental role in chemical bonding, particularly in ionic and
covalent bonds.

A. Ionic Bonding: Electrostatic Attraction Between Ions

 Ionic bonds form due to Coulombic attraction between oppositely charged ions.
 Example: Sodium chloride (NaCl)
o Na loses an electron to form Na⁺.
o Cl gains an electron to form Cl⁻.
o The Na⁺ and Cl⁻ ions attract each other due to Coulomb forces, forming a strong
ionic bond.

Factors Affecting Ionic Bond Strength

1. Charge of Ions – Higher charges lead to stronger attraction (e.g., Mg²⁺O²⁻ has a
stronger bond than Na⁺Cl⁻).
2. Ionic Radius – Smaller ions create stronger Coulomb attractions due to shorter distances.

B. Covalent Bonding: Coulombic Attraction Between Nuclei and Electrons

 In covalent bonds, atoms share electrons.

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,  Coulomb forces govern electron-nucleus attraction while balancing nucleus-nucleus
repulsion.
 Example: Hydrogen molecule (H₂)
o Each H atom has one proton and one electron.
o The two nuclei attract the shared electron pair while repelling each other.
o A stable bond forms when attractive and repulsive forces balance.




3. Coulomb Forces in Intermolecular Interactions
Apart from bonds within molecules, Coulomb forces influence interactions between molecules,
affecting physical properties like boiling points and solubility.

A. Dipole-Dipole Interactions

 Occur between polar molecules with partial positive and negative charges.
 Example: HCl molecules
o H has a partial positive charge (δ⁺), Cl has a partial negative charge (δ⁻).
o Adjacent molecules attract via Coulomb forces.

B. Hydrogen Bonding (Strong Dipole-Dipole Interaction)

 Occurs when H is bonded to highly electronegative elements (N, O, F).
 Example: Water (H₂O)
o O is δ⁻, H is δ⁺ → adjacent molecules attract strongly.
o This explains water’s high boiling point and surface tension.

C. London Dispersion Forces (Induced Dipole Interactions)

 Weak Coulomb forces in nonpolar molecules due to temporary charge fluctuations.
 Example: Noble gases (Ar, Xe) and hydrocarbons.




4. Coulomb Forces in Lattice Structures
In crystal lattices, ions arrange in repeating patterns to maximize Coulomb attraction and
minimize repulsion.

 Example: NaCl Crystal Lattice
o Na⁺ and Cl⁻ ions pack in a stable face-centered cubic structure.
o The lattice energy, governed by Coulomb forces, determines melting point and
solubility.


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