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Hydrogen

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This notes contain a fundamental concept of the topic This includes illustration of my own and also from book and internet Hopefully this helps you in your exams and understanding the concept

Institution
Chemistry

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,↓
Hydrogen forms far more compound than anyother element




.
2
Similarity to alkali metal : Forms oxides ,
halides
,
sulphides and reactivity
"
"Halogens :
resemblance in IE
,
forms diatomic molewle ,
forms hydride

and large no - of covalent .
compound


.
3
Due to resemblance of both Alkali metal a
Halogen and non-resemblance of

both Keep it
makes H to separately in periodic table




.
4 occurance of
t most in (70 % of total
:
I is abundant element the universe
mass)
and principal element in solar atomosphere

Jupiter & Saturn is
majorly
h2
·




Due it earth gravity so 0 15 %
to
light mass escapes only
· .



,




by mass in earth atomosphere.

Combined
·
for 15 4 % .
of mass of earth crust and ocean




hydrogen
.
5
isotopes of : 3 isotopes

>
-
Protium H


>
-
Deuterium ?t (0v) D- Heavy hydrogen
>
- Tritium H

Harold Curey got nobel prize for Separating hydrogen isotope
·




of mass number 2
by physical method .




·
Predominant form Protium

Deuterium form of HD
·
-
0 0156 %
-

of terrestial hydrogen mostly in


·
Tritium -

One atom per 108 protium atoms -




·

Only milium is radioactive and emits 'ow
energy B particles

(ty2 - 12 33
.


yr)

, ·
all have same electronic config so same chemical properties

rate of reaction differ due to diff Bond
Only entral
Dy
.




·
in physical props these isotope differ considerably due to

their large mass difference .




.
6 Preparation of
42 :




i) Lab method :




2n + 2H + > In
&+
+
+2 /In with dil .
Hal)


2n + 2 NaOH >
NaznO2 + 12
Sodium
Zincate



ii) Commercial Production :




210 Electrolysis , Pt
electrodey 24
+
02
Traces of acid/base



·

high purity of 11799 .
95 % ) is obtained by electrolysing
warm
ag . Bacon Soln . blu Ni electrode
,




·
obtained as byproduct in manufacture of Naon and D2


at anode : zaial >
2
+ ze-


at cathode ze 201-
Ho
: + >
1 +




Reyn of HC
high temp
·

Steam on or loke at .




Cntan + 2
+
nH20
1220k
>n(0 + (2n + 1)12
Ni




Nowdd
1270K
Co 312
Chu + H20 Ni
> +


I I
Produce
used to
= water lov Syngas
an
S
methand GHC

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