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Exam (elaborations)

AQA June /2 A-level CHEMISTRY Paper 2 Organic and Physical Chemistry

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A-level CHEMISTRY Paper 2 Organic and Physical Chemistry

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Please write clearly in block capitals.
A-level
Centre Candidate
CHEMISTRY
number number


Paper 2 Organic and Physical Chemistry
Surname

Forename(s)

Candidate re Time allowed: 2 hours
signatu
Materials
For this paper you must have: For Examiner’s Use
 the Periodic Table/Data Booklet, provided as an insert (enclosed) Questio Mark
 a ruler with millimetre measurements n
 a scientific calculator, which you are expected to use where appropriate. 1
2
Instructions
3
 Use black ink or black ball-point pen.
 Fill in the boxes at the top of this page. 4
 Answer all questions. 5
 You must answer the questions in the spaces provided. Do not 6
write outside the box around each page or on blank pages.
7
 If you need extra space for your answer(s), use the lined pages at the end of
this book. Write the question number against your answer(s). 8
 All working must be shown. 9
 Do all rough work in this book. Cross through any work 10
you do not want to be marked.
TOTAL
Information
 The marks for questions are shown in brackets.
 The maximum mark for this paper is 105.




*Jun227405201*
IB/M/Jun22/
E9
7405/2

, 2
Do not
write
Answer all questions in the spaces box
provided.


0 1 An acidified solution of butanone reacts with iodine as shown.

CH3CH2COCH3 + I2 → CH3CH2COCH2I + HI

0 1
.1 Draw the displayed formula for

CH3CH2COCH2I Give the name of

CH3CH2COCH2I
[2 marks]
Displayed formula




Name




*02
IB/M/
*

, 3
Do not
write
0 1 .2 The rate equation for the reaction is box


rate = k[CH3CH2COCH3]
[H+]

Table 1 shows the initial concentrations used in an
experiment.

Table 1

CH3CH2COCH3 I2 H+
Initial concentration / mol 4.35 0.0050 0.82
dm−3 0 5

The initial rate of reaction in this experiment is 1.45 ×10−4 mol dm−3

s−1 Calculate the value of the rate constant, k, for the reaction and
[3 marks]
give its units.




k

Units


0 1 .3 Calculate the initial rate of reaction when all of the initial concentrations are halved.
[1 mark]




Initial rate of reaction mol dm−3 s−1




*03
IB/M/
*

, 4
Do not
write
Question 1 continues on the next page


Turn over ►




*03
IB/M/
*

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