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Summary Unit 1 - Atoms, molecules and stoichiometry

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Summary Unit 1 - Atoms, molecules and stoichiometry

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July 31, 2022
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Atomic Mass Unit

 The mass of a single atom is so small that it is impossible to weigh it directly
 Atomic masses are therefore defined in terms of a standard atom which is called
the unified atomic mass unit
 This unified atomic mass is defined as one-twelfth of the mass of a carbon-12
isotope
 The symbol for the unified atomic mass is u (often Da, Dalton, is used as well)
 1 u = 1.66 x 10-27 kg

Relative atomic mass, Ar

 The relative atomic mass (Ar) of an element is the ratio of the average mass of the
atoms of an element to the unified atomic mass unit
 The relative atomic mass is determined by using the average mass of
the isotopes of a particular element
 The Ar has no units as it is a ratio and the units cancel each other out




Relative isotopic mass

 The relative isotopic mass is the mass of a particular atom of
an isotope compared to the value of the unified atomic mass unit
 Atoms of the same element with a different number of neutrons are called isotopes
 Isotopes are represented by writing the mass number as 20Ne, or neon-20 or Ne-20
o To calculate the average atomic mass of an element the percentage
abundance is taken into account
o Multiply the atomic mass by the percentage abundance for each isotope and
add them all together
o Divide by 100 to get average relative atomic mass
o This is known as the weighted average of the masses of the isotopes

,Relative molecular mass, Mr

 The relative molecular mass (Mr) is the ratio of weighted average mass of a
molecule of a molecular compound to the unified atomic mass unit
 The Mr has no units




 The Mr can be found by adding up the relative atomic masses of all atoms present
in one molecule
 When calculating the Mr the simplest formula for the compound is used, also known
as the formula unit
o Eg. silicon dioxide has a giant covalent structure, however the simplest
formula (the formula unit) is SiO2

, Relative formula mass, Mr

 The relative formula mass (Mr) is used for compounds containing ions
 It has the same units and is calculated in the same way as
the relative molecular mass
 In the table above, the Mr for potassium carbonate, calcium hydroxide and
ammonium sulfates are relative formula masses




Mole & Avogadro Constant
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