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Exam (elaborations)

Exam (elaborations) TEST BANK FOR Organic Chemistry 7th Edition By Pau

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Exam (elaborations) TEST BANK FOR Organic Chemistry 7th Edition By Pau The mass spectra of pentane and isopentane are shown here. Determine which spectrum belongs to which compound. 0 20 43 29 57 72 m/z 40 60 Relative Intensity 80 100 0 20 10 20 30 29 43 57 72 m/z 40 60 Relative Intensity 80 100  Spectroscopy Problems 4. Which of the following compounds gives the mass spectrum shown here? 0 20 44 73 58 30 m/z 40 60 Relative Intensity 80 100 N O O H2N 5. An unknown acid underwent a reaction with 1-butanol. The product of the reaction gave the mass spectrum shown here. What is the product of the reaction, and what acid was used? 0 20 41 57 136138 m/z 40 60 Relative Intensity 80 100  Spectroscopy Problems 6. Identify the compound with molecular formula C9H10O3 that gives the following IR and 1 H NMR spectra. 2 10 9 1 3 2 2 100 90 80 70 60 50 40 30 20 10 0 0.0 0.05 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 2.0 A B S O R B A N C E % T R A N S M I T T A N C E WAVENUMBERS 7. Identify the compound with molecular formula C5H11Br that gives the following 1 H NMR spectrum. 765432 2 6 3 8 1 0 2 1  Spectroscopy Problems 8. Identify the compound with molecular formula C6H12O that gives the following IR and 1 H NMR spectra. 9 9 3 100 90 80 70 60 50 40 30 20 10 0 0.0 0.05 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 2.0 WAVENUMBERS A B S O R B A N C E % T R A N S M I T T A N C E 9. A methyl-substituted benzene is treated with Cl2 in the presence of AlCl3, and a 1 H NMR spectrum is taken of one of the monochlorinated products that is isolated from the reaction mixture. Identify this compound. 2 2 3  Spectroscopy Problem

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