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Chemical Bonding and Structure Summary

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This document summarizes the different types of chemical bonds and how to identify them. Steps and examples are provided. Oxidation numbers are important to learn and the rules haven be given.

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Uploaded on
December 16, 2021
Number of pages
5
Written in
2020/2021
Type
Summary

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'
Bond length distance between atoms when bonded

Bond amount of energy released when
energy

=


°
bona is formed an

§Ñ
distance between nuclei


Energy supplied to BREAK bond

Energy released to FORM new bond .




Atoms bond to become
more STABLE Bond strength strength
: of attraction

shorter bond length =
stronger bond

smaller atoms =
stronger bond

more bonds stronger bond

=




chemical bonding
0
Bonds = forces of attraction : hold atoms together .




Bonding gain stability [octet / noble gas]
0 =




1. Covalent bonds :
A sharing of at least one pair of electrons by two non -
metals


°
Diatomic molecules =
atoms from same element E. H2
g
°
molecules =
atoms from different elements



Electronegativity :
A measure of the tendency of an atom to attract a bonding pair of electrons .




Polar covalent bond :
An intramolecular bond that arises due to unequal sharing of electrons leading to a dipole forming
as a result of electronegativity difference .





EN 1=0

Different atoms






e- not shared equally :
shift to higher EN ( has stronger force)


charges develop =
dipole formed


Non polar covalent bond An intramolecular bond that arises due
-
: to equal sharing of electrons .





EN =
0
diatomic molecules





e- shared
equally

No charges developed .




Polarity of MOLECULE using charge distribution .




Non -


polar molecule : even distribution (no poles) E.g. CH4


Polar molecule :
uneven distribution ( poles) E.g HC1

, Steps to follow


I. Central atom { valence e-

2. Lone pairs of e-

3.
Shape
4. Bond polarity
5. Molecule polarity NOTE !


valency = # of e- to be accepted / donated
tg.HU # of
• valence e- =
outermost electrons

I. Group # valence e- valency # of bonds group # =
# of valence e-

Hydrogen 1 I 1 1

Chlorine 7 7 8-7=1 I




2 .
No central atom or lone pairs

3. :
linear


4 .



g- < I
gt
i.
polar covalent bond

a- It
EN 3,0
__
EN -2,1 -




Sgt , > 8-
H -
'


II :

/ °




i.
polar molecule


1-
g. C02 # of
1 . Group # valence e- valency # of bonds
Types of shapes
carbon 4 4 8-4=4 4

Oxygen 6 6 8-6=2 2 '



Linear


2. Carbon
2 lone
central

pairs on
atom

each oxygen atom .
-


Tetrahedral
o¥o
A
Pyramidal
.



3 . .




0 :C :O 650
.




linear
. ' '
.




4.
g- 1 ft a :
polar covalent bond
O=c
EN -3,0 -
EN -2,5



s . 50=6 g-
i.
non -


polar molecule
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