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Summary Fundamental Organic and Alkenes

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Fundamental Organic and Alkenes

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General formula = algebraic formula that can describe any member of a family of compounds.

Empirical formula = the simplest whole number ratio of atoms of each element in a compound.

Molecular formula = the actual number of atoms of each element in a molecule.

Structural formula = arrangement of atoms, carbon by carbon with attached hydrogen and functional groups.

Skeletal formula = bonds of the carbon skeleton only, with any functional groups.

Displayed formula = shows how the atoms are arranged and the bonds between them.

HOMOLOGOUS SERIES = a bunch of organic compounds that have the same functional group and general formula and
successive members of the series differ by a CH2.

HOMOLOGOUS SERIES PREFIX OR SUFFIX
Alkanes -ane
Alkenes -ene
Haloalkanes Chloro-/bromo-/iodo-
Alcohols -ol /hydrox-
Aldehydes -al
Ketones -one
Cycloalkanes Cyclo- … -ane
Carboxylic acids -oic acid
Esters Alkyl- …-anoate

Aromatic = contain a benzene ring.
Aliphatic = contain carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings.
Alicyclic = if an aliphatic compound contains a non-aromatic ring.
Saturated = single bonds only.
Unsaturated = double bonds or triple bonds or aromatic groups.

Nomenclature = the naming of organic compounds

1 2 3 4 5 6 7 8 9 10
Meth- Eth- Prop- But- Pent- Hex- Sept- Oct- Non- Dec-


Isomers = the same molecular formula but a different arrangement.

CHAIN ISOMERRS Carbon skeleton can be arranged differently.

Similar chemical properties but different physical
property.

POSITIONAL ISOMERS Skeleton and functional group the same but
functional group attached to a different part.
Different physical and chemical properties.
(possibility)

FUNCTIONAL GROUP ISOMERS Same atoms can be arranged into different
functional groups.

Very different physical chemical and physical
properties

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