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3.1.2 - Amount of Substance | AQA A-level Chemistry | Summary Notes

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AQA AS/A-level Chemistry - 3.1.2 - Amount of Substance - Concise summary Notes - A+ Study Notes

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3.1.2 Amount of substance


Ar and Mr

Relative atomic mass (Ar) is the average mass of 1 atom of an element compared to 1/12th of the mass of 1 atom of
carbon-12

Relative molecular mass (Mr) is the average mass of 1 molecule compared to 1/12th of the mass of 1 atom of
carbon-12

The term relative formula mass is used for ionic compounds because ionic compounds don’t exist as molecules



The mole and Avogadro’s constant

A mole is the amount of substance in grams that has the same number of particles in 12 grams of carbon-12 atoms

Avogadro’s constant is the number of particles in 1 mole (Particles = atoms/molecules/ions/electrons/etc)

𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒𝑠 = 𝑚𝑜𝑙𝑒𝑠 𝑜𝑓 𝑠𝑢𝑏𝑠𝑡𝑎𝑛𝑐𝑒 × 𝐴𝑣𝑜𝑔𝑎𝑑𝑟𝑜’𝑠 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡

𝑚𝑜𝑙𝑒𝑠 =

- Mass = grams
- Moles = mol
- Mr = 1 decimal place



Concentration and volume

𝑚𝑜𝑙𝑎𝑟 𝑐𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑡𝑖𝑜𝑛 =

- Molar concentration = 𝑚𝑜𝑙 𝑑𝑚
- Moles = mol
- Volume = 𝑑𝑚

𝑚𝑎𝑠𝑠 𝑐𝑜𝑛𝑐𝑒𝑛𝑡𝑟𝑎𝑡𝑖𝑜𝑛 =

- Mass concentration = 𝑔 𝑑𝑚
- Mass = grams
- Volume = 𝑑𝑚

𝑛𝑒𝑤 𝑑𝑖𝑙𝑢𝑡𝑒𝑑 𝑐𝑜𝑛𝑐 = 𝑜𝑟𝑖𝑔𝑖𝑛𝑎𝑙 𝑐𝑜𝑛𝑐 ×

Concordant results are titres within 0.1 𝑐𝑚 of each other

, 3.1.2 Amount of substance


Density

𝑑𝑒𝑛𝑠𝑖𝑡𝑦 =

The units of density vary depending on the question



Unit conversions

𝑐𝑚 to 𝑑𝑚 divide by 1,000

𝑐𝑚 to 𝑚 divide by 1,000,000

𝑑𝑚 to 𝑚 divide by 1,000

°C to K add 273

kPa to Pa multiply by 1,000

kg to tonnes divide by 1,000

g to kg divide by 1,000

mg to g divide by 1,000

μg to mg divide by 1,000



The 3 Laws

Boyle’s Law is “the product of pressure and volume is a constant as long as the temperature remains constant”
(pressure × volume = constant)

Charles’ Law is “the volume is proportional to the temperature as long as the pressure remains constant” (volume ∝
temperature and volume ÷ temperature = constant)

Gay-Lussac’s Law is “the pressure is proportional to the temperature as long as the volume remains constant”
(pressure ∝ temperature and pressure ÷ temperature = constant)

The combined equation of Boyle’s, Charles’ and Gay Lussac’s Laws:

×
= 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡 𝑓𝑜𝑟 𝑎 𝑓𝑖𝑥𝑒𝑑 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑔𝑎𝑠



The ideal gas equation

𝑝𝑉 = 𝑛𝑅𝑇
- p = pressure = Pa
- V = volume = 𝑚
- n = number of moles

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