Spectrometric
ldentification of
Organic Compounds
,
,Answers for Student Exercises 1 .1 to 1 .5 1
Atom Type # of Atoms Mass Total Mass
Hydrogen 22 1.00783 22.17226
a
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-ethyloctane Oxygen 0 15.9949 0.00000
C10H22 Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 0 Exact Mass 142.17226
- (C2Hs•) +
[ r Rule 3
..
[ r - (CH2=CH2) +
+
Rule 9
b Atom Type # of Atoms Mass Total Mass
Hydrogen 18 1.00783 18.14094
Carbon 10 12.00000 120.00000
Nitrogen 0 14.0031 0.00000
3-butylcyclohex-1-ene Oxygen 0 15.9949 0.00000
C10H18 Sulfur 0 31.9721 0.00000
CnHmXxNyOz IHD Bromine 0 78.9183 0.00000
Index = (n) - (m/2) - (x/2) + (y/2) + 1 = 2 Exact Mass 138.14094
[
[
rr or
- (C4H9 )
•
Rule 5 and 6 .. 0
Rule 6
.-.
r r .. r
- (CH)=CH
- 7 )
[
r r - (C3H7•) \_)/ ..
, @LECTSOLUTIONSSTUVIA
+
• \ /
+
Rule 3