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E Final Organic chemistry 1 (Chem-40010) University of California stereo-chemistry questions.docx

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E Final Organic chemistry 1 (Chem-40010) University of California stereo-chemistry

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E Final Organic chemistry 1 (Chem-
40010) University of California
5.iWhichiNewmaniprojectionishowsitheimostistableiconformationiofitheifollowingicom
pound?




1. WhichiofitheiFischeriprojectionsicorrectlyidepictsitheifollowingicompound?




2. Theifollowingistereoisomersiareirelatedias...

, (a) enantiomers.
(b) diastereomers.
(c) epimers.
(d) identicalicompounds.
3. Whichiofitheifollowingicompoundsiexhibitiopticaliactivity?




4. Determineiwhichiofitheicarboniatomsiinitheifollowingicompoundsiareichiral.ide
termineithei"R"iori"S"idesignationiforithatiatom.

, Determineitheirelationshipibetweenitheitwoimoleculesishown.




a. constitutionaliisomers
b. enantiomers
c. diastereomers
d. identicalimolecules




Whatiisitheicorrectinameiforithisimolecule?i

a. (2R,3R)-2-bromo-3-chlorobutane
b. (2S,3R)-2-bromo-3-chlorobutane
c. (2S,3S)-2-bromo-3-chlorobutane
d. (2R,3S)-2-bromo-3-chlorobutane


Whatiisitheispecificirotationi20[α]Diofitheifollowingimolecule?




a.i4.42o b.i+0.442o c.i+44.2o d.i–i44.2o

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