TEST BANK for Organic Chemistry 6th Edition Smith
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/ All Chapters 1 - 29 / Full Complete
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Page 1q
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
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Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22 Carbonyl Condensation Reactions
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Chapter 23 Amines
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Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25 Pericyclic Reactions
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Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
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Chapter 28 Synthetic Polymers
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Chapter 29 Lipids (Available online)
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, Chapter 1: Structure and Bonding
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1. What is the ground-state electronic configuration of a carbon atom?
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A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
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2. What is the ground-state electronic configuration of a fluorine
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atom?A) 1s2, 2s2, 2p2
q q q B) 1s2, 2s2, 2p3 C) 1s2, 2s2,
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4 2 2 5
2p
q D) 1s , 2s , 2p q q q
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)?A)
q q 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2 q q q q q
B) 1s2, 2s2, 2p6, 3s1
q q q D) 1s2, 2s2, 2p6, 3s2, 3p2 q q q q
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
q q q C) 1s2, 2s2, 2p6, 3s2, 3p5 q q q q
B) 1s2, 2s2, 2p6, 3s2, 3p6
q q q q D) 1s2, 2s2, 2p6, 3s2, 3p4 q q q q
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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, Chapter 1: Structure and q q q
Bonding
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C) They are the outermost electrons. q q q q
D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl q q q
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO q q q
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B) I, IV C) II, III D) II, IV
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10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
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A) I > II > III > IV
q q q q q q C) IV > III > II > I q q q q q q
B) IV > II > I > III
q q q q q q D) IV > II > III > I q q q q q q
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms2 covalent bonds.
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Page 4 q
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/ All Chapters 1 - 29 / Full Complete
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Page 1q
,Chapter 1 Structure and Bonding
q q q q
Chapter 2 Acids and Bases
q q q q
Chapter 3 Introduction to Organic Molecules and Functional Groups
q q q q q q q q
Chapter 4 Alkanes
q q
Chapter 5 Stereochemistry
q q
Chapter 6 Understanding Organic Reactions
q q q q
Chapter 7 Alkyl Halides and Nucleophilic Substitution
q q q q q q
Chapter 8 Alkyl Halides and Elimination Reactions
q q q q q q
Chapter 9 Alcohols, Ethers, and Related Compounds
q q q q q q
Chapter 10 Alkenes and Addition Reactions
q q q q q
Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
q q q q q
Chapter 16 Reactions of Aromatic Compounds
q q q q q
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
q q q q q q q
Oxidation and Reduction
q q q
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
q q q q q
Chapter 19 Carboxylic Acids and Nitriles
q q q q q
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
q q q q q q q q
Substitution
q
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
q q q q q q q q q
Chapter 22 Carbonyl Condensation Reactions
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Chapter 23 Amines
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Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25 Pericyclic Reactions
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Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
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Chapter 28 Synthetic Polymers
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Chapter 29 Lipids (Available online)
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Page 2 q
, Chapter 1: Structure and Bonding
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1. What is the ground-state electronic configuration of a carbon atom?
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A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
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2. What is the ground-state electronic configuration of a fluorine
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atom?A) 1s2, 2s2, 2p2
q q q B) 1s2, 2s2, 2p3 C) 1s2, 2s2,
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4 2 2 5
2p
q D) 1s , 2s , 2p q q q
3. What is the ground-state electronic configuration of a magnesium cation
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(Mg2+)?A)
q q 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2 q q q q q
B) 1s2, 2s2, 2p6, 3s1
q q q D) 1s2, 2s2, 2p6, 3s2, 3p2 q q q q
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
q q q C) 1s2, 2s2, 2p6, 3s2, 3p5 q q q q
B) 1s2, 2s2, 2p6, 3s2, 3p6
q q q q D) 1s2, 2s2, 2p6, 3s2, 3p4 q q q q
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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Page 3 q
, Chapter 1: Structure and q q q
Bonding
q
C) They are the outermost electrons. q q q q
D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl q q q
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO q q q
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II B) I, IV C) II, III D) II, IV
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10. Arrange the following bonds in decreasing order of ionic character, putting the
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mostionic first.
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A) I > II > III > IV
q q q q q q C) IV > III > II > I q q q q q q
B) IV > II > I > III
q q q q q q D) IV > II > III > I q q q q q q
11. Which of the following statements correctly describes the typical number of bonds
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forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
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forms3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
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forms2 covalent bonds.
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