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Summary Notes - Electrode Potentials and Cells

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Understand electrochemical cells, electrode potentials with this focused and easy-to-follow summary. Covers standard electrode potentials, electrochemical cells, cell diagrams Includes worked examples and key definitions AQA/Edexcel/OCR aligned Perfect for Year 13 revision and exam prep Get to grips with electrochemistry in no time – essential for mastering this topic.

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April 8, 2025
Number of pages
5
Written in
2023/2024
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‭Electrochemistry‬

‭Standard‬‭Conditions:‬

‭ oncentration‬
C -‭ ‬ ‭ .0‬‭mol‬‭dm‬‭3‬ ‭(if‬‭gases‬‭involved‬‭in‬‭half‬‭equation)‬‭(H+)‬
1
‭Temperature‬ ‭-‬ ‭298K‬
‭Pressure‬ ‭-‬ ‭100‬‭kPa‬‭(if‬‭gases‬‭involved‬‭in‬‭half‬‭equation)‬
‭Current‬ ‭-‬ ‭0‬‭(use‬‭high‬‭resistance‬‭voltmeter)‬




‭Platinum‬‭used‬‭as‬‭it‬‭is‬‭inert‬‭+‬‭a‬‭conductor‬

, ‭Emf‬‭=‬‭E‬‭(reduced)‬‭-‬‭E‬‭(oxidised)‬




‭The‬‭more‬‭+ve‬‭electrode‬‭gains‬‭electrons‬‭(‬‭+‬‭charge‬‭attracts‬‭electrons)‬

‭ egative‬‭electrode‬ ‭=‬‭cathode‬ =
N ‭ ‬‭oxidation‬
‭Positive‬‭electrode‬ ‭=‬‭anode‬ ‭=‬‭reduction‬
‭More‬‭positive‬‭emf‬‭value‬‭=‬‭more‬
‭likely‬‭to‬‭gain‬‭electrons‬

‭ O‬‭PRoblem‬‭=‬
N
‭More‬‭negative‬‭=‬‭oxidised‬
‭More‬‭positive‬‭=‬‭reduced‬

‭ ALT‬‭BRIDGE:‬‭ions‬‭flow‬
S
‭through‬‭it,‬‭completes‬‭the‬‭circuit‬
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