Smith / All Chapters 1 - 29 / Full Complete
Page 1
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,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxidat
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ion and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
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Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22 Carbonyl Condensation Reactions
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Chapter 23 Amines
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Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25 Pericyclic Reactions
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Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
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Chapter 28 Synthetic Polymers
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Chapter 29 Lipids (Available online)
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Page 2 HQ
, Chapter 1: Structure and Bonding HQ HQ HQ HQ
1. What is the ground- HQ HQ HQ
state electronic configuration of a carbon atom? A) 1s2, 2s2, 2p5
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B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2,2s2,2p4
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2. What is the ground- HQ HQ HQ
state electronic configuration of a fluorine atom?A) 1s2, 2s2, 2p2
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Q H Q HQ HQ
B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2,2s2,2p5
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3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?A)
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1s2, 2s2, 2p6
HQ HQ C) 1s2, 2s2, 2p6, 3s2 HQ HQ HQ
B) 1s2, 2s2, 2p6, 3s1 HQ HQ HQ D) 1s2, 2s2, 2p6, 3s2, 3p2 HQ HQ HQ HQ
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?A)
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1s2, 2s2, 2p6
HQ HQ C) 1s2, 2s2, 2p6, 3s2, 3p5 HQ HQ HQ HQ
B) 1s2, 2s2, 2p6, 3s2, 3p6 HQ HQ HQ HQ D) 1s2, 2s2, 2p6, 3s2, 3p4 HQ HQ HQ HQ
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons. HQ HQ HQ HQ HQ HQ
B) They do not participate in chemical reactions. HQ HQ HQ HQ HQ HQ
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C) They are the outermost electrons. HQ HQ HQ HQ
D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.HQ HQ HQ HQ HQ HQ HQ HQ HQ HQ HQ HQ
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals. HQ HQ HQ HQ HQ HQ HQ HQ HQ HQ
7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl H Q H Q H Q
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO H Q H Q H Q
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II HQ B) I, IV H Q HQ C) II, III H Q HQ D) II, IV HQ HQ
10. Arrange the following bonds in decreasing order of ionic character, putting the mostioni
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c first.
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A) I > II > III > IV
HQ HQ HQ HQ HQ HQ C) IV > III > II > I HQ HQ HQ HQ HQ HQ
B) IV > II > I > III HQ HQ HQ HQ HQ HQ D) IV > II > III > I HQ HQ HQ HQ HQ HQ
11. Which of the following statements correctly describes the typical number of bonds forcarb
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on, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms3 co
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms2 co
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