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Chemistry class 12th Lanthanoids_vs_Actinoids

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Lanthanoids and actinoids are two series of f-block elements with distinct properties. Lanthanoids (atomic numbers 57–71) exhibit a +3 oxidation state and are known for their magnetic, optical, and catalytic applications. They are used in strong magnets, phosphors, and electronics. Actinoids (atomic numbers 89–103) have variable oxidation states and include radioactive elements like uranium and plutonium, crucial for nuclear energy and weaponry. While lanthanoids are relatively stable and less reactive, actinoids are highly reactive, especially in the presence of oxygen and water. Actinoids are mostly synthetic and radioactive, whereas lanthanoids are naturally occurring.

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Lanthanoids and Actinoids - Characteristics & Comparison


Introduction:
Lanthanoids and actinoids are two series of inner transition elements in the periodic table.
Lanthanoids consist of elements with atomic numbers 57 to 71, while actinoids include elements
with atomic numbers 89 to 103. These elements are placed separately in the periodic table due to
their unique properties and electronic configurations.


General Characteristics of Lanthanoids:
1. Lanthanoids are soft metals with high reactivity.
2. They exhibit a +3 oxidation state (some also show +2 and +4 states).
3. Lanthanoids have a gradual decrease in atomic and ionic radii, known as lanthanoid contraction.
4. They show high melting and boiling points.
5. Most lanthanoids are paramagnetic due to unpaired electrons.
6. They form colored ions and complex compounds.
7. Lanthanoids have low electronegativity and low ionization energy.


General Characteristics of Actinoids:
1. Actinoids are radioactive elements, with some being synthetic.
2. They exhibit variable oxidation states (+3, +4, +5, +6, and +7).
3. Actinoids have smaller atomic radii due to actinoid contraction.
4. They have higher densities and are generally more reactive than lanthanoids.
5. Actinoids show significant paramagnetic and complex-forming properties.
6. Many actinoids are used as nuclear fuel (e.g., uranium and plutonium).
7. Actinoids form colored compounds and have strong radioactive properties.


Comparison: Lanthanoids vs. Actinoids
1. **Occurrence:** Lanthanoids are mostly natural, while many actinoids are synthetic.
2. **Radioactivity:** Lanthanoids are stable; actinoids are mostly radioactive.
3. **Oxidation States:** Lanthanoids mainly show +3 oxidation state; actinoids exhibit multiple
oxidation states.
4. **Density & Hardness:** Actinoids are denser and harder than lanthanoids.
5. **Magnetic Properties:** Both are paramagnetic, but actinoids have more complex magnetism.
6. **Chemical Reactivity:** Actinoids are more reactive, especially with air and water.
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