1. Classification & Nomenclature
Alkyl Halides
Classification:
Primary (1°): Halogen attached to a carbon bonded to one alkyl group.
Example: CH CH CH (1° Br bromide).
Secondary (2°): Halogen attached to a carbon bonded to two alkyl groups.
Example: (CH ) CHCl (2° chloride).
Tertiary (3°): Halogen attached to a carbon bonded to three alkyl groups.
Example: (CH ) CBr (3° bromide).
Nomenclature:
, IUPAC: Prefix (fluoro, chloro, bromo, iodo) + parent alkane.
Example: 3-iodopentane.
Common Name: Alkyl halide.
Example: tert-Butyl chloride.
Aryl Halides
Classification: Halogen attached directly to a benzene ring.
Ortho (o): Halogen at position 1,2.
Meta (m): Halogen at position 1,3.
Para (p): Halogen at position 1,4.
Alkyl Halides
Classification:
Primary (1°): Halogen attached to a carbon bonded to one alkyl group.
Example: CH CH CH (1° Br bromide).
Secondary (2°): Halogen attached to a carbon bonded to two alkyl groups.
Example: (CH ) CHCl (2° chloride).
Tertiary (3°): Halogen attached to a carbon bonded to three alkyl groups.
Example: (CH ) CBr (3° bromide).
Nomenclature:
, IUPAC: Prefix (fluoro, chloro, bromo, iodo) + parent alkane.
Example: 3-iodopentane.
Common Name: Alkyl halide.
Example: tert-Butyl chloride.
Aryl Halides
Classification: Halogen attached directly to a benzene ring.
Ortho (o): Halogen at position 1,2.
Meta (m): Halogen at position 1,3.
Para (p): Halogen at position 1,4.