Smith / All Chapters 1 - 29 / Full Complete
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,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents; Oxida
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tion and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives-
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Nucleophilic Acyl Substitution
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Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22 Carbonyl Condensation Reactions
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Chapter 23 Amines
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Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25 Pericyclic Reactions
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Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
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Chapter 28 Synthetic Polymers
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Chapter 29 Lipids (Available online)
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, Chapter 1: Structure and Bonding DB DB DB DB
1. What is the ground-DB DB DB
state electronic configuration of a carbon atom? A) 1s2, 2s2, 2p5
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B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
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2. What is the ground-DB DB DB
state electronic configuration of a fluorine atom?A) 1s2, 2s2, 2p2
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B D B DB DB
B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
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3. What is the ground-DB DB DB
state electronic configuration of a magnesium cation (Mg2+)?A) 1s2, 2s2, 2p6
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C) 1s2, 2s2, 2p6, 3s2 DB DB DB
B) 1s2, 2s2, 2p6, 3s1 DB DB DB D) 1s2, 2s2, 2p6, 3s2, 3p2 DB DB DB DB
4. What is the ground-state electronic configuration of a chlorine anion (Cl—
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)?A) 1s2, 2s2, 2p6
D
B DB C) 1s2, 2s2, 2p6, 3s2, 3p5
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B) 1s2, 2s2, 2p6, 3s2, 3p6 DB DB DB DB D) 1s2, 2s2, 2p6, 3s2, 3p4 DB DB DB DB
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.DB DB DB DB DB DB
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding DB DB DB DB
C) They are the outermost electrons.
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D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to another.
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B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
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C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl D B D B D B
8. Which of the following molecules has nonpolar covalent bonds?
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A) HCl B) N2 C) CHCl3 D) NO D B D B D B
9. Which of the following molecules contain both covalent and ionic bonds?
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A) I, II DB B) I, IV C) II, III D) II, IV
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10. Arrange the following bonds in decreasing order of ionic character, putting the mosti
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B
onic first.
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A) I > II > III > IV
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B) IV > II > I > IIIDB DB DB DB DB DB D) IV > II > III > I DB DB DB DB DB DB
11. Which of the following statements correctly describes the typical number of bonds for
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B
carbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms
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B
3 covalent bonds.
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B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms
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B
2 covalent bonds.
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