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Mechanism of radical bromination of alkenes

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University of Texas CH320M SN1, SN2, E1, E2, Alkene, Alkyne, mechanism map, reactions, summary sheets Mechanism of radical bromination of alkenes

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University Of Texas - Austin
Course
CH320 (CH320M)








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Institution
University Of Texas - Austin
Course
CH320 (CH320M)
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Uploaded on
October 24, 2024
Number of pages
1
Written in
2020/2021
Type
Class notes
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Shabbir
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Mechanism of Radical Bromination of Alkanes Page # 1


Step 1: Initiation:
or
Br Br
hν
iii iii
homolytic (or) heat
cleavage
radical
consumed
Propagation H H
H H NNN I 1
Br H C c H BI
H C C H I 1
Step-2 H H
H H
i.ardaianaiaegnas.in




nr raareaeaierae

Regioselectivity:

Br 2
EE Br Br Step-3

hν H H


BI t H tI d1 BI
H H
A coupling
haloalkane
Br Br
Termination
coupling H H F annihilation
Br + NABr I I g of
H C C Br radicals
Product
1 I k
Step-4 L
H H H H
H H H H
coupling p I l
H C C + Br
N f H c c c c H
Step-5
H H l I I 1
H H H H
H

ND Y fc
H H H H H

H C C
+
C C H H E c c H
Step-6
H H H H
H H H H
H H H H

H C C + H C C
Step-7
H H H H
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