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Alkene mechanisms summary sheet

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University of Texas CH320M SN1, SN2, E1, E2, Alkene, Alkyne, mechanism map, reactions, summary sheets

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University Of Texas - Austin
Course
CH320 (CH320M)








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Institution
University Of Texas - Austin
Course
CH320 (CH320M)
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Uploaded on
October 24, 2024
Number of pages
3
Written in
2021/2022
Type
Summary

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Hydrohalogenation


MARKOVNIKOV addhalogen tothe moresubstitutedcarbon
NO STEREOSELECTIVITY
CARBOCATION REARRANGEMENT hydrideshift


Ex
Ha u
t j

at
the c i
H

O
Etc O



HBr Br
HALOALKENE



NON MARKOVNIKOV halogengoeson the least substituted carbonatom

Ex
Br Br
I i
TE I
Rook

5 YX
Yg rook Br


HBR NON SELECTIVE
I
poor m Br
bothcisandtrans




Acid Catalyzed Hydration

MARKOVNIKOV OH goes onmoresubstitutedcarbon

NOSTEREOSELECTIVITY racemicmixture isformed if there is a chiral center
CARBOCATIONREARRANGEMENT

Ex7 OH
cat H2504 racemic lit adding an alcohol like
a H2O CHZOH justremove the it

andfollowsamerules

re
H CatH2504 Off
H2O 1


Int A OHH ALCOHOL
azo
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