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Chapter 13 - Electrophilic and Nucleophilic Aromatic Substitution (Test Bank)

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Organic Chemistry 10th Edition by Francis Carey - Test Bank

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1. What is the product of the following reaction?




A. isobutylbenzene
B. sec-butylbenzene
C. 2-methyl-1-phenylpropene
D. tert-butylbenzene

Bloom's Level: 3. Apply
Chapter: 13
Difficulty: Hard
Gradable: automatic
Section: 13.06
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




2. The major product(s) in the nitration of benzoic acid is(are)

A. mixture of ortho and para-nitrobenzoic acid.
B. nitrobenzene.
C. meta-nitrobenzoic acid.
D. nitrobenzene and para-nitrobenzoic acid.

Accessibility: Keyboard Navigation
Bloom's Level: 3. Apply
Chapter: 13
Difficulty: Medium
Gradable: automatic
Section: 13.13
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




13-1
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

,3. Which of the following aromatic compounds reacts faster than benzene in electrophilic
aromatic bromination?




A. A
B. B
C. C
D. D

Bloom's Level: 4. Analyze
Chapter: 13
Difficulty: Medium
Gradable: automatic
Section: 13.12
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




4. Nitration of benzoic acid has a reaction rate which is __________ than the nitration rate
of benzene and gives primarily the _____________ product(s).
A. slower, meta
B. faster, ortho, para
C. slower, ortho, para
D. faster, meta

Accessibility: Keyboard Navigation
Bloom's Level: 2. Understand
Chapter: 13
Difficulty: Medium
Gradable: automatic
Section: 13.13
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




13-2
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

,5. Which one of the following is the electrophile in the reaction shown below?




A. benzene
B. NO3¯
C. NO2+
D. H2SO4

Bloom's Level: 1. Remember
Chapter: 13
Difficulty: Easy
Gradable: automatic
Section: 13.03
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




6. What is the electrophile in the Friedel-Crafts alkylation reaction below?




A. AlCl3
B. Cl¯
C. benzene
+
D. (CH3)3C
Bloom's Level: 2. Understand
Chapter: 13
Difficulty: Easy
Gradable: automatic
Section: 13.06
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




13-3
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

, 7. Which point on the potential energy diagram corresponds to the species shown to the
right for the electrophilic bromination of benzene with Br 2/FeBr3?




A. A
B. B
C. C
D. D

Bloom's Level: 2. Understand
Chapter: 13
Difficulty: Medium
Gradable: automatic
Section: 13.05
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




8. Which species below best depicts the electrophile in the FeBr 3-catalyzed bromination of
benzene?
A. Br2
B. FeBr4-
C.



D. FeBr3

Bloom's Level: 1. Remember
Chapter: 13
Difficulty: Easy
Gradable: automatic
Section: 13.05
Subtopic: Electrophilic aromatic substitution (EAS) reactions
Topic: Aromatic Compounds




13-4
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.

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