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Carbonyls and tautomerisation

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introduction to carbonyls and keto forms

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Chemistry 2X









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University of Glasgow
Course
Chemistry 2X
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Uploaded on
March 10, 2022
Number of pages
8
Written in
2021/2022
Type
Class notes
Professor(s)
Dr soler
Contains
Carbonyls chemistry

Subjects

  • tautomers
  • keto
  • carbonyls

Content preview

📍
lecture 1- carbonyls and
tautomerisation
Date: @January 11, 2022

Topic:

key words Notes
carbonyl=electrophile C=O carbonyl




sp2 hybridised
sp2 hybridisation at C carbonyl compound's are planar giving
120 degrees bond angle




lecture 1- carbonyls and tautomerisation 1

, since the carbonyls are polarised
oxygen is the electronegative atom and pulls electrons to itself
making it electrophilic


nucleophilic attack
the nucleophile attacks the carbonyl (electrophilic) carbon




order of reactivity




reactivity
aldehydes> ketones are most reactive to NU attack

then in decreasing order f reactivity it is> ester~ carboxylic acid
> amide




lecture 1- carbonyls and tautomerisation 2
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