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Summary Unit 3.2.1 - Periodicity NOTES

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A-level AQA Chemistry Periodicity New spec Applicable to most exam boards

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Unit 2
Topic 1: Periodicity




The Periodic Table arranges the known elements according to ​proton number​. All the
elements along a ​period​have the same number of ​electron shells​. All the elements down a
​group​have the same number of ​outer electrons​, this number is indicated by the group
number.

Elements are classified into ​blocks​within the Periodic Table that show electron
configuration:

● s-block = groups 1 and 2
● p-block = groups 3 to 0
● d-block = transition metals
● f-block = radioactive elements

These different electron configurations are often ​linked to other trends​within the Periodic
Table. Periodicity is the study of these trends.




Atomic Radius

Along a ​period​, atomic radius ​decreases​. This is due to an ​increased nuclear charge​for the
same number of electron shells. The outer electrons are pulled in closer to the nucleus as
the increased charge produces a ​greater attraction​. As a result, the atomic radius for that
element is reduced.




Down a ​group​, atomic radius ​increases​. With each increment down a group, an electron
shell is added each time. This increases the distance between the outer electrons and the
nucleus, reducing the power of attraction​. More shells also increases electron ​shielding​
where the inner shells create a ‘barrier’ that blocks the attractive forces. Therefore the
​nuclear attraction is reduced​further and atomic radius increases.

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