Intramolecular aldol Guías de estudio, Notas de estudios & Resúmenes

Chapter 23 Review: Condensation Reactions -- Chemistry 2322-003, Spring 1992 Última actualización de este documento:   hace

1) The Aldol Condensation - enolation and the steps involved - more successful for aldehydes but less successful for ketones 2) Dehydration of Aldol Products 3) Mixed (or Crossed) Condensations - including discussions of steric hindrance - explanation of when these reactions work well - spontaneous dehydration 4) Intramolecular Aldol Condensations

Orgo II 4 Última actualización de este documento:   hace

Most notes are types and structure drawn with chemdraw, some mechanism, and quite cheat sheet are shown in neat handwriting produced on ipad. Most reactions show detailed step-wise mechanism (with electron transfer arrows) Material covered are as shown below Carbonyl rearrangements: Schmidt, Beckmann, Curtius, Wolff Enols and Enolates: ketone deuteration, alpha-halogenations, alpha-alkylations, enamine alkylations, decarboxylation Aldol Reaction: general, condensation, Cross Aldol condensation, ...