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Exam (elaborations)

Problems to Chapter 1

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polymers in Problem 1

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1. Show by equations the overall chemical reactions involved in the synthesis of

polymers from

a. CH2=CH – CO2H



b.

c. H2N – (CH2)5 – NH2 + ClCO – (CH2)5 – COCl

d. HO – (CH2)5 – CO2H




e.

f. CH2=CH – F


Solution



Polymer Structure &
Monomer Polymer name
Repeating unit


a. CH2=CH-CO2H

Poly(acrylic acid)




Poly(oxetane) or
Poly(trimethylene oxide)
or
b. Poly(trimethylene ether)

, c.




Poly (Ɛ-caprolactone) or
d.
PCL




e.
[1]

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