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Summary

Summary Chapter 15 - Haloalkanes

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OCR CHEMISTRY A-LEVEL HALOALKANES SUMMARY.

Content preview

HA h 0 A L R A N E S i

P RE f i x i f h U O RO f
lH hO Ro CL
B R OMO Br
l ODO l

NO t A t l O N i Rk

ht N f O R MU h A NIA BU T I HA L 0 a t N R t P h A CES
l H D R OG t N
Y


C O M P O U N DS LO N T A l N I N G
C AR B ON
H Y D RO G E N
o O XY G t N
HA L U G E N AT LEAST D
L L AS S l f l l A T l O N i


HI l
fl H fl fl fl H
H C C Cl H ll CC H HC CC H
I i l
H HH
i
HH H CHH

PR I M A R Y S t l 0 N D A Ry t t n i l A Ry

l LA S S l f l l A t l 0 N BAS E D ON NO l A R BO N
A T OM S A T TA L H t D t O l AR B O N A TO M B O N AED
T O H A L O Gt N

REA l i l V i t y i

HA L 0 a t N A TO MS V E R Y th t l t R O N E G A T l V E
SO C X B ON D l S P O h AR t P E R M A N t N t D I POLE
I N D V L ED
tt s
C f
c.ci niisaaffe.n wniesarsour C x
I Br E h E L T R O N E G A T l v t sO
C I B0 N D L E S S P OL A R B VT S T RO N a t R
NV l hE OPH I L L l C SUB S T I i U i l O N i

NU l h E O P H l L t i S PE l l ES T HA T DON A t t s l t s
h ON t pA l h O f E L EC T R ON S
tO t h E C T RO N D E f I l l t Ift
l AR B ON AT O M

, NU L L EOP H I L L l e A TT A l k i t t l t L t C t RO N
DE f I l I t I l AR B ON
A T O M A T TA C R E D
BY NV C h t O P H I L t


NTI't 5 7 Nii CH t Br

Nu C OU h D Bt i OH IN NH H2O
H Y D R O Ly S I S Of HA h 0A L R A N t s i

H Y DRO L Y S i s i l A L R t A L T IO N
CH E MI I NV U L VING
WA T t R l A Q U t O U S S O L U T l O N Of
A H Y D R 0X I D t THA T CA U S E S
TH E B RE AK I N G U t A B ON D I N
A MO L t l U L t
NU l h t O P H I L t H Y DRO x i D t l O NS

EG CH CH Br t OH lag CH CHIH t Br
REFLUX

YH HH
HC
i CftBr
1
H C I
O H t iBr
H H H H MECHANISM
i
OH

cO N D I t l O N S
R t f l U X
A QU t O U S SL N
RE AG t N t I f OR N UC h E O P H I L t I i
ROH IP 0 T A S S I U M H Y D R 0 X I D t I
NAOH LSOD I U M H Y D R 0 X I D E

RA T E Of HY D R O L Y S I S O f H A L OA l n A N E S i

L f A C TO R S i
BO N D PO L A R l t y
BOND E N T H A L P Y

fLUORO ALKANES 1ODO ALKANES


SLOWEST FASTEST

w t A k t R THE B ON D fA STE R R EA l T l O N AS
L ESS E N t R Gy NE E D t D T O O V E R C O ME BO ND
R AT E D E T E R MI N t D BY S t R t N G TH Of BOND
NO i PO L A R I T Y

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July 11, 2020
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Written in
2019/2020
Type
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