1_h~dJoco.rbon= ,. . a-com . pound
~- - ma.ci; . -upor n11ctrogen
v"
i <1tu.fo. t Q.1.,1. = o.11~1n9 (l~Ond.S JO.C001pOtAnd."3lt-hO.i:G.r'oO{l' ,.
onctco.rb.ononi~- o 1.1ph o n c: - s;-ro.lgh
-
-~- __ __
nyo.,o
tcho·1,-gor'cc:..rbCll"lS .
~- --=:: 0
Q: l\ltt~ r.f"ccuci,,,on -.;-;:,sp.,~ 1
d S t:-r u"
\11\SQtUl'O. ted' d outi~ ·Jtr1pii,l>On
vn.\1Vit c.Clfli,tll llUAIIP~
C.0'/0.Ll'ntS an P"''"'- I' ",,o.'"'"
-
oO \l bl e bond ,f c a n cl c,
. rnen·sfYl
,so - U. m -_ sor<le. W
0L
A
-,
A< CM- , .f"'rn~O'Jr
; ·
, • • ,. dif'ferenQ.rc-b.
co.t'bor> con
-
~=•'~ '· _, 1
fUnChO na I group' p M Of , •• MO u.w.U- "'"'"~ ,.,,.,,,;blO. """'"" 1MLO.c.uJ.a.< ,.,,mu to, -'<>- = b< ~'".,-..,.,..,,I
oub~o•
/1lC 11-' ,ch, ml< 01 ,to.Cf on rffl '"M o. ""oU u,.L< ca,i i,"•• - O ~ gf1JIJ.f
oH, • ' " ' ' " ' '
forrnu.lo. e•<n.Lctu.ra
d •= •:~;;;: ".
Ff<' ,en t .g . o l l ,::.om~rso~
L
I
toeoch Olher +-<> f!Om" tong ch01,n.r.
"'"" •,.,,. . . . - •=":' = •." '
homalogou."::. sea·~::. - p.q.rni I u q:. rY"I l..Q._(v.,Ut.l / h
. ~'· ,.,,;..,-...,,.. ~.,, w f e sc,me
R.).ncnon c,.I group. £'.o.c.h succ.£.Ss.Wtc member cAiffic,t"l n9 by CA-lz.
,=_~......= ~...£~~ ~
rtnruen
.__ ,..____ --
.I'll~
-..=.!r~=-----
-
.....
~ -..._J~---=-;,,
Cs H ,o
"'!'' l>on folmfl,or\CIS" to c,tllcr oto"'' 1,1"-tOt ,IUb-JIII~
"" cyclic n or ban .n ro "'' ;mned ..
in o ri n_g .(~1i!.pref-1X: c~clO-) h•logtnl
~ •. . mo LJ2w.lOr ,,,,roL.LlO., nurnbe< +t!jpe sicele ,o. c ,_,.,nphf,ed organ;c
u.r© •S 0
" can> h <f O 1<>'0'P'""ent. (doe""' shOUl now 1-0rrnul o. •4 O \\ne ,eprc=n" 0
-= · ~ ...,..."""""c.....--..... sing l e. bend . 0
t "':c"." on ,ncecsedion
- co.rbOl"l c...uce thelJ're)o1noo) ~H'\ C\ 1\0 l C2 i'1 6O 00
N AM « M< ~ A•C o o,,i, nc b c~os,ne ernp 1d co c_,slmpLeSt whole nu.mbec .-, \wO 1;nes ,
t'YP ( ~ne , -o.r,e.,-y"e) .,,.i-riplebOr>d Ula~ 00 ,..,d ratio g1U(lh ~ Corl:1-0c-+ CHLO c arbo r> o.+-orn
s. 9 e.. qener +-c.o.fbon~) genera fOrrn u o. -o. gebro.1c f-OffYIUla.fOr e..nd oi:-11ne. represen cti '
clou. l::lle " I~ l ..__...., I I - I ·
2) no. oi:. c.o.rtons: . forr,,u
onb0-C1<.- , - - - - - - - ' di'<:.plo.ye.d"'
onyfY'lernberQf'.o ho!Ylolog:ius_
re10.tive ot
s~Pes.
po~i-ncn1ng ts o. 39roup. i
~ 'l..- suLQ,t-o.\ fOrmu 10 torepf<1.Se.nt
,\rne\h , .) e;h -,,) prop ~, bu.t s.\ Pen• a«>ms and \h<.lr bondS. <:!l'"' nnd o.romotit compoundt.
O
o;) h•• >-l hepc <-) OU q) non io.) d ec w-uctu.ra l-smal.lRDt de><> i L co ,hoW ,U nc H on• I g"""' m u,t ' ""''""'~·
3) $\·d.R_ c h o.1h t-y pe. o. I"\ d pos: ih on :
- - r oc onr_A .. ''C q
arrargement<'showsbwh1ch gfOUP!sO.re. 1,oocla.d)
ll
e. q ~n \ (Ir u b\J. t - i - en('_ '-
l,l. t(.U'l~o(l-1,:(H 2.C.l-lz(,H3
1ll
'-~
~i==U.<.d "•Ide t,canchc.S' oc "ac1<,il g,o~ps'' \. 01\{.
ornesend 1n -yl- Gc.ne.ro.l
l\lr NI
a.---OI (H J (CH,\
B , cC1
3 o.cornotic • so,pc. or all the
co.rbo,-, atoms round.. ar~ In
0
I:, t,\\(A Cl-\ 1:11,'l lii\o>IP. I'\':?,'° ""' b<c• •= e nn9
eomrnon ., dL, ch a,ns , c.
,
c-H2.Ct-13c+-I =-
,
P' '"'~lo Cn H ,n H
l-l3=rnerf1&L CH2.Cl-l,3 :o. e..\-h,Y l
a prop YL
\
_ol\~,c
ono
c~l'YK'-
vt.l '-r »
•Nne.nachelY\iCC41 r<mC:hOI"\ t-Q.\lMPIO.tl!., reottant- bOJldStirrnrand
,roctu,>, fOm'\ ntW b on ct,. CovoL•nt nd, ace bro••••~
,w,c,enc
. bO
<OO t IS th, lo n '" o,,i b ll ""e,wcvntc>• l e, .s ,o<va ti <th'o,hn,, an mctron poi' ,_
thnt ront11ins . .• . I .c«oHu(,,J "'"'"";". ""'""~Wfi!r,.J
mll lti fU nc h On 0, l g co LAP "'-""' j n,Lu.0-'- 'o;r,..-en• -pounds w,>hSOM• +ht b«O. Ing Oj' 0 C. b " " " . both e f ,om Cb. 90 " OM ...
P~bunds If. r:
'2. 9 · - ~ r1
. . "'
,(.,_''h \ , , -z.-.c:ns
iYW.1-h~l It
C -~
.. , - 1-1
h~\IHh~
-.r
-@)'/
rnoL«u lor~orrnulO.S.are~rne.rs, ~o~t,-,e."ooncle.datoms \;-oforf'Y'\ ions."
uOrh c\'10111.1 • f.urichona.l groU-.ps could 1::>e 0.1-
so1n,no.
•• f,ercoc poslho•eo• c-ono i n .
"+-ht- bre.ot.ing of- o-c,I?.
,l,
' " " " "~"H""' rht. bond to /Oml ,odl co LS· .
4 Ll. ;r-c.L ...., CL• +
l 0
11,)he.re. QO.Ch of- 1-nt 1,ondl.d r0ms ttl~
rl @:3)7 • Mo"-w.lw ,onlo,n,ng ,.,,., >noLwmu lo
orcorbOlll 4• ,,,~., " ' >n on ""'""' I o,
IOt\QQ.SI-ChQirJ :s t'llen the ~lAl- cli [-fQrtnt-FUt'\ChonO.l 13rO\J.P• 1-\ "9 · QJh CtM 1-1 ~ C. - C.H -4 ~I.J_c.,tro n .
number =rboos ;n t>~ longese ch ,""'" wl ' Stru"'1CGI Isom ,cs ,, OIYI! W\OiiLU W H - iJ'-,- l,OLJ'"__, H _ 1+ • . _ a HaC ~ot.: ~K3
O n . most
"°'""" .,•
bU+diW<rtntstrulfilCOL \J ' ct
0
• Chere•• 0 clw.bL I C
•6=rbon, , • boncj ' •• , . . ..,,nrnu mote.cw.ts hUVC th•W••· H ,'., ..,~ .,,.. . '"'" ,...,._ '
,
'«h ' . • h=. d . . . ' " " " MOU.CUI OJ f-0 """" <V '" fh ougn fh "I
S =m~from <" corbo• ,.'>-•ehS<' Chain . nov< ,r c,nt cunc•ronol O!!UPS ,
end "' -
•mavtMIA\t Ol-0. poi• 0/-fil.lAYOr\3•
..,.,.o.n. ""!!•"'"'
-· 4-, 4- -dimemuL"
W<~meri,yl.s =min9 ,,om ""' ==• ;Qtl'V, ol'iltA,.._,
U"~.:::.;~,;...;,= ...; 1,n11 isom"" u:iM,nMnds.o..re. v~n301oun . £LI NI 1NATlON
- H H
= .
:7 ADDITION I I
notQ.·.o'2..-Qth\lL
'
c
.
,._...1 · "1-h ~l
::1 , 4- ,--.-u11Yh:.- y\X,')(-)-,en..Q..
l.n, ·tworwct-o.nts,
-
oneproduer
e H, .., 11
·Y· H _,..c-:::c , ,-1+6r2
--} _ - Br
2- -~Br-
II \ I H
H 1-1
•onH~o.u-o..nt , H-c-c-
tu;oprod.ucts
1-j
I I
OH
1-i H (IUd
~ (C\tC\ l~St
Qor!vJ,nwc0ne
sulil.'3TITlfflCN 1"1 I H ,,H
\- CJ_-
c :::.cyclohe.xone •o.no.1-ornorqrourof , + OH- ---l- H-C--0\1 ·,c:=. C \- \-l 0
... o.tom:s lsNploctd\:Jy e~ . H ·- C- CL / 2.
o.11o+h e,r a. lil mor grou~
,1_1 H 'H
1~
~a.toms.
~- - ma.ci; . -upor n11ctrogen
v"
i <1tu.fo. t Q.1.,1. = o.11~1n9 (l~Ond.S JO.C001pOtAnd."3lt-hO.i:G.r'oO{l' ,.
onctco.rb.ononi~- o 1.1ph o n c: - s;-ro.lgh
-
-~- __ __
nyo.,o
tcho·1,-gor'cc:..rbCll"lS .
~- --=:: 0
Q: l\ltt~ r.f"ccuci,,,on -.;-;:,sp.,~ 1
d S t:-r u"
\11\SQtUl'O. ted' d outi~ ·Jtr1pii,l>On
vn.\1Vit c.Clfli,tll llUAIIP~
C.0'/0.Ll'ntS an P"''"'- I' ",,o.'"'"
-
oO \l bl e bond ,f c a n cl c,
. rnen·sfYl
,so - U. m -_ sor<le. W
0L
A
-,
A< CM- , .f"'rn~O'Jr
; ·
, • • ,. dif'ferenQ.rc-b.
co.t'bor> con
-
~=•'~ '· _, 1
fUnChO na I group' p M Of , •• MO u.w.U- "'"'"~ ,.,,.,,,;blO. """'"" 1MLO.c.uJ.a.< ,.,,mu to, -'<>- = b< ~'".,-..,.,..,,I
oub~o•
/1lC 11-' ,ch, ml< 01 ,to.Cf on rffl '"M o. ""oU u,.L< ca,i i,"•• - O ~ gf1JIJ.f
oH, • ' " ' ' " ' '
forrnu.lo. e•<n.Lctu.ra
d •= •:~;;;: ".
Ff<' ,en t .g . o l l ,::.om~rso~
L
I
toeoch Olher +-<> f!Om" tong ch01,n.r.
"'"" •,.,,. . . . - •=":' = •." '
homalogou."::. sea·~::. - p.q.rni I u q:. rY"I l..Q._(v.,Ut.l / h
. ~'· ,.,,;..,-...,,.. ~.,, w f e sc,me
R.).ncnon c,.I group. £'.o.c.h succ.£.Ss.Wtc member cAiffic,t"l n9 by CA-lz.
,=_~......= ~...£~~ ~
rtnruen
.__ ,..____ --
.I'll~
-..=.!r~=-----
-
.....
~ -..._J~---=-;,,
Cs H ,o
"'!'' l>on folmfl,or\CIS" to c,tllcr oto"'' 1,1"-tOt ,IUb-JIII~
"" cyclic n or ban .n ro "'' ;mned ..
in o ri n_g .(~1i!.pref-1X: c~clO-) h•logtnl
~ •. . mo LJ2w.lOr ,,,,roL.LlO., nurnbe< +t!jpe sicele ,o. c ,_,.,nphf,ed organ;c
u.r© •S 0
" can> h <f O 1<>'0'P'""ent. (doe""' shOUl now 1-0rrnul o. •4 O \\ne ,eprc=n" 0
-= · ~ ...,..."""""c.....--..... sing l e. bend . 0
t "':c"." on ,ncecsedion
- co.rbOl"l c...uce thelJ're)o1noo) ~H'\ C\ 1\0 l C2 i'1 6O 00
N AM « M< ~ A•C o o,,i, nc b c~os,ne ernp 1d co c_,slmpLeSt whole nu.mbec .-, \wO 1;nes ,
t'YP ( ~ne , -o.r,e.,-y"e) .,,.i-riplebOr>d Ula~ 00 ,..,d ratio g1U(lh ~ Corl:1-0c-+ CHLO c arbo r> o.+-orn
s. 9 e.. qener +-c.o.fbon~) genera fOrrn u o. -o. gebro.1c f-OffYIUla.fOr e..nd oi:-11ne. represen cti '
clou. l::lle " I~ l ..__...., I I - I ·
2) no. oi:. c.o.rtons: . forr,,u
onb0-C1<.- , - - - - - - - ' di'<:.plo.ye.d"'
onyfY'lernberQf'.o ho!Ylolog:ius_
re10.tive ot
s~Pes.
po~i-ncn1ng ts o. 39roup. i
~ 'l..- suLQ,t-o.\ fOrmu 10 torepf<1.Se.nt
,\rne\h , .) e;h -,,) prop ~, bu.t s.\ Pen• a«>ms and \h<.lr bondS. <:!l'"' nnd o.romotit compoundt.
O
o;) h•• >-l hepc <-) OU q) non io.) d ec w-uctu.ra l-smal.lRDt de><> i L co ,hoW ,U nc H on• I g"""' m u,t ' ""''""'~·
3) $\·d.R_ c h o.1h t-y pe. o. I"\ d pos: ih on :
- - r oc onr_A .. ''C q
arrargement<'showsbwh1ch gfOUP!sO.re. 1,oocla.d)
ll
e. q ~n \ (Ir u b\J. t - i - en('_ '-
l,l. t(.U'l~o(l-1,:(H 2.C.l-lz(,H3
1ll
'-~
~i==U.<.d "•Ide t,canchc.S' oc "ac1<,il g,o~ps'' \. 01\{.
ornesend 1n -yl- Gc.ne.ro.l
l\lr NI
a.---OI (H J (CH,\
B , cC1
3 o.cornotic • so,pc. or all the
co.rbo,-, atoms round.. ar~ In
0
I:, t,\\(A Cl-\ 1:11,'l lii\o>IP. I'\':?,'° ""' b<c• •= e nn9
eomrnon ., dL, ch a,ns , c.
,
c-H2.Ct-13c+-I =-
,
P' '"'~lo Cn H ,n H
l-l3=rnerf1&L CH2.Cl-l,3 :o. e..\-h,Y l
a prop YL
\
_ol\~,c
ono
c~l'YK'-
vt.l '-r »
•Nne.nachelY\iCC41 r<mC:hOI"\ t-Q.\lMPIO.tl!., reottant- bOJldStirrnrand
,roctu,>, fOm'\ ntW b on ct,. CovoL•nt nd, ace bro••••~
,w,c,enc
. bO
<OO t IS th, lo n '" o,,i b ll ""e,wcvntc>• l e, .s ,o<va ti <th'o,hn,, an mctron poi' ,_
thnt ront11ins . .• . I .c«oHu(,,J "'"'"";". ""'""~Wfi!r,.J
mll lti fU nc h On 0, l g co LAP "'-""' j n,Lu.0-'- 'o;r,..-en• -pounds w,>hSOM• +ht b«O. Ing Oj' 0 C. b " " " . both e f ,om Cb. 90 " OM ...
P~bunds If. r:
'2. 9 · - ~ r1
. . "'
,(.,_''h \ , , -z.-.c:ns
iYW.1-h~l It
C -~
.. , - 1-1
h~\IHh~
-.r
-@)'/
rnoL«u lor~orrnulO.S.are~rne.rs, ~o~t,-,e."ooncle.datoms \;-oforf'Y'\ ions."
uOrh c\'10111.1 • f.urichona.l groU-.ps could 1::>e 0.1-
so1n,no.
•• f,ercoc poslho•eo• c-ono i n .
"+-ht- bre.ot.ing of- o-c,I?.
,l,
' " " " "~"H""' rht. bond to /Oml ,odl co LS· .
4 Ll. ;r-c.L ...., CL• +
l 0
11,)he.re. QO.Ch of- 1-nt 1,ondl.d r0ms ttl~
rl @:3)7 • Mo"-w.lw ,onlo,n,ng ,.,,., >noLwmu lo
orcorbOlll 4• ,,,~., " ' >n on ""'""' I o,
IOt\QQ.SI-ChQirJ :s t'llen the ~lAl- cli [-fQrtnt-FUt'\ChonO.l 13rO\J.P• 1-\ "9 · QJh CtM 1-1 ~ C. - C.H -4 ~I.J_c.,tro n .
number =rboos ;n t>~ longese ch ,""'" wl ' Stru"'1CGI Isom ,cs ,, OIYI! W\OiiLU W H - iJ'-,- l,OLJ'"__, H _ 1+ • . _ a HaC ~ot.: ~K3
O n . most
"°'""" .,•
bU+diW<rtntstrulfilCOL \J ' ct
0
• Chere•• 0 clw.bL I C
•6=rbon, , • boncj ' •• , . . ..,,nrnu mote.cw.ts hUVC th•W••· H ,'., ..,~ .,,.. . '"'" ,...,._ '
,
'«h ' . • h=. d . . . ' " " " MOU.CUI OJ f-0 """" <V '" fh ougn fh "I
S =m~from <" corbo• ,.'>-•ehS<' Chain . nov< ,r c,nt cunc•ronol O!!UPS ,
end "' -
•mavtMIA\t Ol-0. poi• 0/-fil.lAYOr\3•
..,.,.o.n. ""!!•"'"'
-· 4-, 4- -dimemuL"
W<~meri,yl.s =min9 ,,om ""' ==• ;Qtl'V, ol'iltA,.._,
U"~.:::.;~,;...;,= ...; 1,n11 isom"" u:iM,nMnds.o..re. v~n301oun . £LI NI 1NATlON
- H H
= .
:7 ADDITION I I
notQ.·.o'2..-Qth\lL
'
c
.
,._...1 · "1-h ~l
::1 , 4- ,--.-u11Yh:.- y\X,')(-)-,en..Q..
l.n, ·tworwct-o.nts,
-
oneproduer
e H, .., 11
·Y· H _,..c-:::c , ,-1+6r2
--} _ - Br
2- -~Br-
II \ I H
H 1-1
•onH~o.u-o..nt , H-c-c-
tu;oprod.ucts
1-j
I I
OH
1-i H (IUd
~ (C\tC\ l~St
Qor!vJ,nwc0ne
sulil.'3TITlfflCN 1"1 I H ,,H
\- CJ_-
c :::.cyclohe.xone •o.no.1-ornorqrourof , + OH- ---l- H-C--0\1 ·,c:=. C \- \-l 0
... o.tom:s lsNploctd\:Jy e~ . H ·- C- CL / 2.
o.11o+h e,r a. lil mor grou~
,1_1 H 'H
1~
~a.toms.
