ORGANIC CHE MISTRY
I
"
II
' "
my
:#
polythene
(0 t
H10
fi
, amino ""
Ef ¥
""
"
:/
'
-
H H n combustion
Polymer , " ithen.ie
to
,
E. Heman . ftp.p.POlyaomide
toddy C =L Nickel H H
⑤
H
f- c- c- H condensation
-
catalyst
" H H
A IK9M @
hydrolysis
'
'
> polymerisation
Iropnilic free radical substitution H
bromoptropane
nig
H t
*ogeitUV light 2-
Athene """"¥i%HaI0AI Kane
inzmoieiuies
y
, :
q, "
H -
i. e- H %:
I, It hydrogen halide
①
+
Electrophilic addition
:oii¥÷÷÷i÷÷ :÷÷÷i÷: ÷÷÷÷
fain(
,
~
is:* :
" "
:*:*:*
.
÷.
refh.tk
/ C
H
H, P04 catalyst
-
I
, µ
in"
::÷÷÷÷÷,
" "
"
"
÷:c :c . ¥ .no .
.
Secondary alcohol
'
H
primary
reduction
all hot
H OH
addition
catalytic
ffydyoygynifpg.gg g.
,,ca+aµ+
+ * ,
www.qq.jq#oandd..,ono,,.o*owwuaeopni,i addition a ,oµµ
,
.im//taaidintiihnII i: : :ian:. nff
µ µ
If
.
,
" t '""
Nucleophilic On
naBHy +
④ Distillation HI, I,
I'
'
1%1 mran.mu.
oh,
ICHI Kiko , this 04
µ If p I / @
+
+
Iffy kilrzo , this 04
✓
✓
Polyester Aldehyde ketone it "
÷÷÷i÷÷÷÷
iii. man," .
.
"
:*:* . ".
÷:
2x CO0H groups dicnromate fo, ]
ethanol , +
ZX0H groups Kzlrz 0,14504
✓ L
carboxylic acid
'
board Into"n%
⑥
"
carboxylate ,
salts Imm¥a%×idt
it +0 tainan etnanoicacid
% % violent reaction
ACYI chloride
¥¥÷¥I¥¥±%det¥¥I
^ ⇐ -
carbonate primary amine
\
' +
c- c ,
-
←
'
O
-
Nat
,
Acid hydrolysis
/
tion
iumetnanoate ne + ammonia
secondary amide
""
i
meat
"
ii. K
,
'
primary amide
"
,
"
N methyl ethanamide
O CHZCH , it
-
go
-
Alkaline hydrolysis ( saponification) H C c
ethylpwpanoate
- -
+ OH can
-
' '
H NH ,
heat under reflux
ethan amide
MECHANISMS
1- mechanism
for electrophilic addition for an athene 't
hydrogen halide
2- mechanism
for electrophilic addition for an alkene + halogen 6- Mechanism of nucleophilic addition -
elimination
3- mechanism for nucleophilic substitution
for hydrolysis otahaloalkane Using NQ0H
4- mechanism addition to carbonyl compounds
for nucleophilic ,
↳
tNaBH4 /-
benzene 1
electrophilic
substitution
-
capbonyt.nu/eophiIi additi#
↳ haloalkane -_
nucleophilic substitution
+
NACNIHT
5- mechanism alkene -_
electrophilic addition
for free radical substitution - initiation , propagation '- termination
I
"
II
' "
my
:#
polythene
(0 t
H10
fi
, amino ""
Ef ¥
""
"
:/
'
-
H H n combustion
Polymer , " ithen.ie
to
,
E. Heman . ftp.p.POlyaomide
toddy C =L Nickel H H
⑤
H
f- c- c- H condensation
-
catalyst
" H H
A IK9M @
hydrolysis
'
'
> polymerisation
Iropnilic free radical substitution H
bromoptropane
nig
H t
*ogeitUV light 2-
Athene """"¥i%HaI0AI Kane
inzmoieiuies
y
, :
q, "
H -
i. e- H %:
I, It hydrogen halide
①
+
Electrophilic addition
:oii¥÷÷÷i÷÷ :÷÷÷i÷: ÷÷÷÷
fain(
,
~
is:* :
" "
:*:*:*
.
÷.
refh.tk
/ C
H
H, P04 catalyst
-
I
, µ
in"
::÷÷÷÷÷,
" "
"
"
÷:c :c . ¥ .no .
.
Secondary alcohol
'
H
primary
reduction
all hot
H OH
addition
catalytic
ffydyoygynifpg.gg g.
,,ca+aµ+
+ * ,
www.qq.jq#oandd..,ono,,.o*owwuaeopni,i addition a ,oµµ
,
.im//taaidintiihnII i: : :ian:. nff
µ µ
If
.
,
" t '""
Nucleophilic On
naBHy +
④ Distillation HI, I,
I'
'
1%1 mran.mu.
oh,
ICHI Kiko , this 04
µ If p I / @
+
+
Iffy kilrzo , this 04
✓
✓
Polyester Aldehyde ketone it "
÷÷÷i÷÷÷÷
iii. man," .
.
"
:*:* . ".
÷:
2x CO0H groups dicnromate fo, ]
ethanol , +
ZX0H groups Kzlrz 0,14504
✓ L
carboxylic acid
'
board Into"n%
⑥
"
carboxylate ,
salts Imm¥a%×idt
it +0 tainan etnanoicacid
% % violent reaction
ACYI chloride
¥¥÷¥I¥¥±%det¥¥I
^ ⇐ -
carbonate primary amine
\
' +
c- c ,
-
←
'
O
-
Nat
,
Acid hydrolysis
/
tion
iumetnanoate ne + ammonia
secondary amide
""
i
meat
"
ii. K
,
'
primary amide
"
,
"
N methyl ethanamide
O CHZCH , it
-
go
-
Alkaline hydrolysis ( saponification) H C c
ethylpwpanoate
- -
+ OH can
-
' '
H NH ,
heat under reflux
ethan amide
MECHANISMS
1- mechanism
for electrophilic addition for an athene 't
hydrogen halide
2- mechanism
for electrophilic addition for an alkene + halogen 6- Mechanism of nucleophilic addition -
elimination
3- mechanism for nucleophilic substitution
for hydrolysis otahaloalkane Using NQ0H
4- mechanism addition to carbonyl compounds
for nucleophilic ,
↳
tNaBH4 /-
benzene 1
electrophilic
substitution
-
capbonyt.nu/eophiIi additi#
↳ haloalkane -_
nucleophilic substitution
+
NACNIHT
5- mechanism alkene -_
electrophilic addition
for free radical substitution - initiation , propagation '- termination
