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Summary A2 Unit 2: Amines

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Summary of Amines for Chemistry A2 Unit 2 CCEA GCE

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Naming Amines

PrimaryAmines onlyonecarbonatom directlybonded tothenitrogen atom



Finn a
iii in n

ethylamine
Tropane
2 amino


Secondary amines two carbon atoms directlybondedtothe nitrogenatom



i i
a n
ii ii n


dimethylamine diethylamine


Tertiaryamines threecarbon atoms directlybonded to the nitrogen atom




in 42
trimethylamine
Phenylamine

, Properties Amines
of

Boiling Points
Minimum
at intuit C's
s

form H Bonds which require a lotofenergytobreak highbp
Amines
alkanes
only haveweakvow betweenmolecules easilybroken

Primary Secontiary Tertiary
nigubp guy
Aschainlength bp dueto value

branchingfrom 1 2 3 reducescontactbetweenneighbouring
molecules reduced strength vow so lower
of bp
3 cannot bebond to eachother as no H

Solubility

size Kininmananti n

Cnz

Smallamines are soluble in water
Hbondsform betweenshortchainamines I 420
Solubilityfallsoff as chaingetslonger as it becomes more difficulttoform
Hbonds dueto increased vow between molecules

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