TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
An An An An
Chapter 2 Acids and Bases
An An An An
Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
An An
Chapter 5 Stereochemistry
An An
Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
An An An An An An An An
Substitution
An
Chapter 21
An Substitution Reactions of Carbonyl Compounds at the α-Carbon
An An An An An An An An
Chapter 22
An Carbonyl Condensation Reactions
An An An
Chapter 23
An Amines
An
Chapter 24
An Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
An An An An An An
Chapter 25
An Pericyclic Reactions
An An
Chapter 26
An Carbohydrates
An
Chapter 27
An Amino Acids and Proteins
An An An An
Chapter 28
An Synthetic Polymers
An An
Chapter 29
An Lipids (Available online)
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Page 2
, Chapter 1: Structure and Bonding An An An An
1. What is the ground-state electronic configuration of a carbon
An An An An An An An An
atom? A) 1s2, 2s2, 2p5
An An B) 1s2, 2s2, 2p2 C) 1s2,
A n An An A n An An A n
2 6 2 2 4
2s , 2p
An An D) 1s , 2s , 2p A n An An
2. What is the ground-state electronic configuration of a fluorine
An An An An An An An An
atom?A) 1s2, 2s2, 2p2
An nA A n B) 1s2, 2s2, 2p3 C) 1s2,
An An A n An An A n
2s2, 2p4
An An D) 1s2, 2s2, 2p5 A n An An
3. What is the ground-state electronic configuration of a magnesium cation
An An An An An An An An An
(Mg2+)?A)
An nA 1s2, 2s2, 2p6 C) 1s2, 2s2, An An An
2p6, 3s2
An An
B) 1s2, 2s2, 2p6, 3s1 An An An D) 1s2, 2s2, 2p6, 3s2, 3p2
An An An An
4. What is the ground-state electronic configuration of a chlorine anion
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An(Cl—)?A) nA 1s2, 2s2, 2p6 C) An An
1s2, 2s2, 2p6, 3s2, 3p5
An An An An
B) 1s2, 2s2, 2p6, 3s2, 3p6
An An An An D) 1s2, 2s2, 2p6, 3s2, 3p4
An An An An
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
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B) They do not participate in chemical reactions.
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Page 3
, Chapter 1: Structure and Bonding
C) They are the outermost electrons.
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D) They reveal the period number of a second-row element.
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6. Which of the following statements about bonding is true?
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A) Covalent bonds result from the transfer of electrons from one element to
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another.
An
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
An An An An An An An An An An An An An
C) Ionic bonds result from the sharing of electrons between two non-metals.
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D) Covalent bonds result from the sharing of electrons between two metals.
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7. Which of the following would you expect to have ionic bonds?
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A) CO B) FBr C) NF3 D) NaCl A n A n A n
8. Which of the following molecules has nonpolar covalent bonds?
An An An An An An An An
A) HCl B) N2 C) CHCl3 D) NO A n A n A n
9. Which of the following molecules contain both covalent and ionic bonds?
An An An An An An An An An An
A) I, II B)
An A n I, IVC)
An A n II, III D) II, IV
An An An
10. Arrange the following bonds in decreasing order of ionic character, putting
An An An An An An An An An An
the mostionic first.
An An nA An
A) I > II > III > IV
An An An An An An C) IV > III > II > I An An An An An An
B) IV > II > I > III
An An An An An An D) IV > II > III > I An An An An An An
11. Which of the following statements correctly describes the typical number of
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bonds forcarbon, nitrogen, and oxygen in most neutral organic molecules?
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A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
An An An An An An An An An An An
forms3 covalent bonds.
An nA An An
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
An An An An An An An An An An An
forms2 covalent bonds.
An nA An An
Page 4
Smith / All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding
An An An An
Chapter 2 Acids and Bases
An An An An
Chapter 3 Introduction to Organic Molecules and Functional Groups
An An An An An An An An
Chapter 4 Alkanes
An An
Chapter 5 Stereochemistry
An An
Chapter 6 Understanding Organic Reactions
An An An An
Chapter 7 Alkyl Halides and Nucleophilic Substitution
An An An An An An
Chapter 8 Alkyl Halides and Elimination Reactions
An An An An An An
Chapter 9 Alcohols, Ethers, and Related Compounds
An An An An An An
Chapter 10 Alkenes and Addition Reactions
An An An An An
Chapter 11 Alkynes and Synthesis
An An An An
Chapter 12 Oxidation and Reduction
An An An An
Spectroscopy A Mass Spectrometry
An An An
Spectroscopy B Infrared Spectroscopy
An An An
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
An An An
Chapter 14 Conjugation, Resonance, and Dienes
An An An An An
Chapter 15 Benzene and Aromatic Compounds
An An An An An
Chapter 16 Reactions of Aromatic Compounds
An An An An An
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
An An An An An An An
Oxidation and Reduction
An An An
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
An An An An An
Chapter 19 Carboxylic Acids and Nitriles
An An An An An
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
An An An An An An An An
Substitution
An
Chapter 21
An Substitution Reactions of Carbonyl Compounds at the α-Carbon
An An An An An An An An
Chapter 22
An Carbonyl Condensation Reactions
An An An
Chapter 23
An Amines
An
Chapter 24
An Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
An An An An An An
Chapter 25
An Pericyclic Reactions
An An
Chapter 26
An Carbohydrates
An
Chapter 27
An Amino Acids and Proteins
An An An An
Chapter 28
An Synthetic Polymers
An An
Chapter 29
An Lipids (Available online)
An An An
Page 2
, Chapter 1: Structure and Bonding An An An An
1. What is the ground-state electronic configuration of a carbon
An An An An An An An An
atom? A) 1s2, 2s2, 2p5
An An B) 1s2, 2s2, 2p2 C) 1s2,
A n An An A n An An A n
2 6 2 2 4
2s , 2p
An An D) 1s , 2s , 2p A n An An
2. What is the ground-state electronic configuration of a fluorine
An An An An An An An An
atom?A) 1s2, 2s2, 2p2
An nA A n B) 1s2, 2s2, 2p3 C) 1s2,
An An A n An An A n
2s2, 2p4
An An D) 1s2, 2s2, 2p5 A n An An
3. What is the ground-state electronic configuration of a magnesium cation
An An An An An An An An An
(Mg2+)?A)
An nA 1s2, 2s2, 2p6 C) 1s2, 2s2, An An An
2p6, 3s2
An An
B) 1s2, 2s2, 2p6, 3s1 An An An D) 1s2, 2s2, 2p6, 3s2, 3p2
An An An An
4. What is the ground-state electronic configuration of a chlorine anion
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An(Cl—)?A) nA 1s2, 2s2, 2p6 C) An An
1s2, 2s2, 2p6, 3s2, 3p5
An An An An
B) 1s2, 2s2, 2p6, 3s2, 3p6
An An An An D) 1s2, 2s2, 2p6, 3s2, 3p4
An An An An
5. Which of the following statements about valence electrons is true?
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A) They are the most tightly held electrons.
An An An An An An
B) They do not participate in chemical reactions.
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Page 3
, Chapter 1: Structure and Bonding
C) They are the outermost electrons.
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D) They reveal the period number of a second-row element.
An An An An An An An An
6. Which of the following statements about bonding is true?
An An An An An An An An
A) Covalent bonds result from the transfer of electrons from one element to
An An An An An An An An An An An
another.
An
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
An An An An An An An An An An An An An
C) Ionic bonds result from the sharing of electrons between two non-metals.
An An An An An An An An An An
D) Covalent bonds result from the sharing of electrons between two metals.
An An An An An An An An An An
7. Which of the following would you expect to have ionic bonds?
An An An An An An An An An An
A) CO B) FBr C) NF3 D) NaCl A n A n A n
8. Which of the following molecules has nonpolar covalent bonds?
An An An An An An An An
A) HCl B) N2 C) CHCl3 D) NO A n A n A n
9. Which of the following molecules contain both covalent and ionic bonds?
An An An An An An An An An An
A) I, II B)
An A n I, IVC)
An A n II, III D) II, IV
An An An
10. Arrange the following bonds in decreasing order of ionic character, putting
An An An An An An An An An An
the mostionic first.
An An nA An
A) I > II > III > IV
An An An An An An C) IV > III > II > I An An An An An An
B) IV > II > I > III
An An An An An An D) IV > II > III > I An An An An An An
11. Which of the following statements correctly describes the typical number of
An An An An An An An An An An
bonds forcarbon, nitrogen, and oxygen in most neutral organic molecules?
An An nA An An An An An An An An
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen
An An An An An An An An An An An
forms3 covalent bonds.
An nA An An
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen
An An An An An An An An An An An
forms2 covalent bonds.
An nA An An
Page 4
