Page 1
b
,Chapter 1 Structure and Bonding
b b b b
Chapter 2 Acids and Bases
b b b b
Chapter 3 Introduction to Organic Molecules and Functional Groups
b b b b b b b b
Chapter 4 Alkanes
b b
Chapter 5 Stereochemistry
b b
Chapter 6 Understanding Organic Reactions
b b b b
Chapter 7 Alkyl Halides and Nucleophilic Substitution
b b b b b b
Chapter 8 Alkyl Halides and Elimination Reactions
b b b b b b
Chapter 9 Alcohols, Ethers, and Related Compounds
b b b b b b
Chapter 10 Alkenes and Addition Reactions
b b b b b
Chapter 11 Alkynes and Synthesis
b b b b
Chapter 12 Oxidation and Reduction
b b b b
Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
b b b
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
b b b b b
Chapter 13 Radical Reactions
b b b
Chapter 14 Conjugation, Resonance, and Dienes
b b b b b
Chapter 15 Benzene and Aromatic Compounds
b b b b b
Chapter 16 Reactions of Aromatic Compounds
b b b b b
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
b b b b b b b
Oxidation and Reduction
b b b
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
b b b b b
Chapter 19 Carboxylic Acids and Nitriles
b b b b b
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
b b b b b b b b b
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
b b b b b b b b b
Chapter 22 Carbonyl Condensation Reactions
b b b b
Chapter 23 Amines
b b
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
b b b b b b b
Chapter 25 Pericyclic Reactions
b b b
Chapter 26 Carbohydrates
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Chapter 27 Amino Acids and Proteins
b b b b b
Chapter 28 Synthetic Polymers
b b b
Chapter 29 Lipids (Available online)
b b b b
Page 2 b
, Chapter 1: Structure and Bonding b b b b
1. What is the ground-state electronic configuration of a carbon atom? A)
b b b b b b b b b b
1s2, 2s2, 2p5
b b B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
b b b b b b b b b b
2. What is the ground-state electronic configuration of a fluorine atom?A)
b b b b b b b b b b
1s2, 2s2, 2p2
b b B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
b b b b b b b b b b
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?A)
b b b b b b b b b b b
1s2, 2s2, 2p6
b b C) 1s2, 2s2, 2p6, 3s2 b b b
B) 1s2, 2s2, 2p6, 3s1 b b b D) 1s2, 2s2, 2p6, 3s2, 3p2 b b b b
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?A)
b b b b b b b b b b b
1s2, 2s2, 2p6
b b C) 1s2, 2s2, 2p6, 3s2, 3p5 b b b b
B) 1s2, 2s2, 2p6, 3s2, 3p6
b b b b D) 1s2, 2s2, 2p6,3s2, 3p4 b b b b
5. Which of the following statements about valence electrons is true?
b b b b b b b b b
A) They are the most tightly held electrons.
b b b b b b
B) They do not participate in chemical reactions.
b b b b b b
Page 3 b
, Chapter 1: Structure and Bonding b b b b
C) They are the outermost electrons. b b b b
D) They reveal the period number of a second-row element.
b b b b b b b b
6. Which of the following statements about bonding is true?
b b b b b b b b
A) Covalent bonds result from the transfer of electrons from one element to another.
b b b b b b b b b b b b
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
b b b b b b b b b b b b b
C) Ionic bonds result from the sharing of electrons between two non-metals.
b b b b b b b b b b
D) Covalent bonds result from the sharing of electrons between two metals. b b b b b b b b b b
7. Which of the following would you expect to have ionic bonds?
b b b b b b b b b b
A) CO B) FBr C) NF3 D) NaCl b b b
8. Which of the following molecules has nonpolar covalent bonds?
b b b b b b b b
A) HCl B) N2 C) CHCl3 D) NO b b b
9. Which of the following molecules contain both covalent and ionic bonds?
b b b b b b b b b b
A) I, II b B) I, IV b b C) II, III b b D) II, IV b b
10. Arrange the following bonds in decreasing order of ionic character, putting the
b b b b b b b b b b b
mostionic first.
b b b
A) I > II > III > IV
b b b b b b C) IV > III > II > I b b b b b b
B) IV > II > I > III
b b b b b b D) IV > II > III > I b b b b b b
11. Which of the following statements correctly describes the typical number of bonds
b b b b b b b b b b b
forcarbon, nitrogen, and oxygen in most neutral organic molecules?
b b b b b b b b b b
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms3
b b b b b b b b b b b b b
covalent bonds.
b b
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms2
b b b b b b b b b b b b b
covalent bonds.
b b
Page 4 b
b
,Chapter 1 Structure and Bonding
b b b b
Chapter 2 Acids and Bases
b b b b
Chapter 3 Introduction to Organic Molecules and Functional Groups
b b b b b b b b
Chapter 4 Alkanes
b b
Chapter 5 Stereochemistry
b b
Chapter 6 Understanding Organic Reactions
b b b b
Chapter 7 Alkyl Halides and Nucleophilic Substitution
b b b b b b
Chapter 8 Alkyl Halides and Elimination Reactions
b b b b b b
Chapter 9 Alcohols, Ethers, and Related Compounds
b b b b b b
Chapter 10 Alkenes and Addition Reactions
b b b b b
Chapter 11 Alkynes and Synthesis
b b b b
Chapter 12 Oxidation and Reduction
b b b b
Spectroscopy A Mass Spectrometry
b b b
Spectroscopy B Infrared Spectroscopy
b b b
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
b b b b b
Chapter 13 Radical Reactions
b b b
Chapter 14 Conjugation, Resonance, and Dienes
b b b b b
Chapter 15 Benzene and Aromatic Compounds
b b b b b
Chapter 16 Reactions of Aromatic Compounds
b b b b b
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
b b b b b b b
Oxidation and Reduction
b b b
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
b b b b b
Chapter 19 Carboxylic Acids and Nitriles
b b b b b
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
b b b b b b b b b
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
b b b b b b b b b
Chapter 22 Carbonyl Condensation Reactions
b b b b
Chapter 23 Amines
b b
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
b b b b b b b
Chapter 25 Pericyclic Reactions
b b b
Chapter 26 Carbohydrates
b b
Chapter 27 Amino Acids and Proteins
b b b b b
Chapter 28 Synthetic Polymers
b b b
Chapter 29 Lipids (Available online)
b b b b
Page 2 b
, Chapter 1: Structure and Bonding b b b b
1. What is the ground-state electronic configuration of a carbon atom? A)
b b b b b b b b b b
1s2, 2s2, 2p5
b b B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
b b b b b b b b b b
2. What is the ground-state electronic configuration of a fluorine atom?A)
b b b b b b b b b b
1s2, 2s2, 2p2
b b B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
b b b b b b b b b b
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?A)
b b b b b b b b b b b
1s2, 2s2, 2p6
b b C) 1s2, 2s2, 2p6, 3s2 b b b
B) 1s2, 2s2, 2p6, 3s1 b b b D) 1s2, 2s2, 2p6, 3s2, 3p2 b b b b
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?A)
b b b b b b b b b b b
1s2, 2s2, 2p6
b b C) 1s2, 2s2, 2p6, 3s2, 3p5 b b b b
B) 1s2, 2s2, 2p6, 3s2, 3p6
b b b b D) 1s2, 2s2, 2p6,3s2, 3p4 b b b b
5. Which of the following statements about valence electrons is true?
b b b b b b b b b
A) They are the most tightly held electrons.
b b b b b b
B) They do not participate in chemical reactions.
b b b b b b
Page 3 b
, Chapter 1: Structure and Bonding b b b b
C) They are the outermost electrons. b b b b
D) They reveal the period number of a second-row element.
b b b b b b b b
6. Which of the following statements about bonding is true?
b b b b b b b b
A) Covalent bonds result from the transfer of electrons from one element to another.
b b b b b b b b b b b b
B) Ionic bonds result from the transfer of electrons from a metal to a non-metal.
b b b b b b b b b b b b b
C) Ionic bonds result from the sharing of electrons between two non-metals.
b b b b b b b b b b
D) Covalent bonds result from the sharing of electrons between two metals. b b b b b b b b b b
7. Which of the following would you expect to have ionic bonds?
b b b b b b b b b b
A) CO B) FBr C) NF3 D) NaCl b b b
8. Which of the following molecules has nonpolar covalent bonds?
b b b b b b b b
A) HCl B) N2 C) CHCl3 D) NO b b b
9. Which of the following molecules contain both covalent and ionic bonds?
b b b b b b b b b b
A) I, II b B) I, IV b b C) II, III b b D) II, IV b b
10. Arrange the following bonds in decreasing order of ionic character, putting the
b b b b b b b b b b b
mostionic first.
b b b
A) I > II > III > IV
b b b b b b C) IV > III > II > I b b b b b b
B) IV > II > I > III
b b b b b b D) IV > II > III > I b b b b b b
11. Which of the following statements correctly describes the typical number of bonds
b b b b b b b b b b b
forcarbon, nitrogen, and oxygen in most neutral organic molecules?
b b b b b b b b b b
A) Carbon forms 4 covalent bonds, nitrogen forms 2 covalent bonds and oxygen forms3
b b b b b b b b b b b b b
covalent bonds.
b b
B) Carbon forms 4 covalent bonds, nitrogen forms 3 covalent bonds and oxygen forms2
b b b b b b b b b b b b b
covalent bonds.
b b
Page 4 b
