TEST BANK for Organic Chemistry
6th Edition Smith /
All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding Chapter
2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups Chapter 4
Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions Chapter
9 Alcohols, Ethers, and Related Compounds Chapter 10
Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis Chapter
12 Oxidation and Reduction Spectroscopy
A Mass Spectrometry Spectroscopy B
Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy Chapter 13
Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes Chapter 15
Benzene and Aromatic Compounds Chapter 16 Reactions of
Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition Chapter 19
Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis Chapter
25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers Chapter 29
Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
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, Chapter 1: Structure and Bonding
C) They sare sthe soutermost selectrons.
D) They sreveal sthe speriod snumber sof sa ssecond-row selement.
6. Which sof sthe sfollowing sstatements sabout sbonding sis strue?
A) Covalent sbonds sresult sfrom sthe stransfer sof selectrons sfrom sone selement sto s another.
B) Ionic sbonds sresult s from sthe stransfer sof selectrons sfrom sa smetal sto sa snon-metal.
C) Ionic sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo snon-metals.
D) Covalent sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo smetals.
7. Which sof sthe sfollowing swould syou sexpect s to shave sionic sbonds?
A) CO B) s sFBr C) s NF3 D) s sNaCl
8. Which sof sthe sfollowing s molecules shas snonpolar scovalent sbonds?
A) HCl B) s N2 C) s CHCl3 D) s sNO
9. Which sof sthe sfollowing s molecules scontain sboth scovalent s and sionic sbonds?
A) I, sII B) s sI, sIV C) s sII, sIII D) sII, sIV
10. Arrange sthe sfollowing sbonds sin sdecreasing sorder sof sionic scharacter, sputting sthe
smost s ionic s first.
A) I s> sII s> sIII s> sIV C) IV s> sIII s> sII s> sI
B) IV s> sII s> sI s> sIII D) IV s> sII s> sIII s> sI
11. Which sof sthe sfollowing sstatements scorrectly sdescribes sthe stypical snumber sof sbonds
sfor s carbon, snitrogen, sand soxygen sin smost s neutral sorganic smolecules?
A) Carbon sforms s4 scovalent s bonds, snitrogen sforms s2 scovalent sbonds sand soxygen
sforms s 3 scovalent s bonds.
B) Carbon sforms s4 scovalent s bonds, snitrogen sforms s3 scovalent sbonds sand soxygen
sforms s 2 scovalent s bonds.
Page 4
6th Edition Smith /
All Chapters 1 - 29 / Full Complete
Page 1
,Chapter 1 Structure and Bonding Chapter
2 Acids and Bases
Chapter 3 Introduction to Organic Molecules and Functional Groups Chapter 4
Alkanes
Chapter 5 Stereochemistry
Chapter 6 Understanding Organic Reactions
Chapter 7 Alkyl Halides and Nucleophilic Substitution
Chapter 8 Alkyl Halides and Elimination Reactions Chapter
9 Alcohols, Ethers, and Related Compounds Chapter 10
Alkenes and Addition Reactions
Chapter 11 Alkynes and Synthesis Chapter
12 Oxidation and Reduction Spectroscopy
A Mass Spectrometry Spectroscopy B
Infrared Spectroscopy
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy Chapter 13
Radical Reactions
Chapter 14 Conjugation, Resonance, and Dienes Chapter 15
Benzene and Aromatic Compounds Chapter 16 Reactions of
Aromatic Compounds
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
Oxidation and Reduction
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition Chapter 19
Carboxylic Acids and Nitriles
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl Substitution
Chapter 21 Substitution Reactions of Carbonyl Compounds at the α-Carbon
Chapter 22 Carbonyl Condensation Reactions
Chapter 23 Amines
Chapter 24 Carbon-Carbon Bond-Forming Reactions in Organic Synthesis Chapter
25 Pericyclic Reactions
Chapter 26 Carbohydrates
Chapter 27 Amino Acids and Proteins
Chapter 28 Synthetic Polymers Chapter 29
Lipids (Available online)
Page 2
, Chapter 1: Structure and Bonding
1. What is the ground-state electronic configuration of a carbon atom?
A) 1s2, 2s2, 2p5 B) 1s2, 2s2, 2p2 C) 1s2, 2s2, 2p6 D) 1s2, 2s2, 2p4
2. What is the ground-state electronic configuration of a fluorine atom?
A) 1s2, 2s2, 2p2 B) 1s2, 2s2, 2p3 C) 1s2, 2s2, 2p4 D) 1s2, 2s2, 2p5
3. What is the ground-state electronic configuration of a magnesium cation (Mg2+)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2
B) 1s2, 2s2, 2p6, 3s1 D) 1s2, 2s2, 2p6, 3s2, 3p2
4. What is the ground-state electronic configuration of a chlorine anion (Cl—)?
A) 1s2, 2s2, 2p6 C) 1s2, 2s2, 2p6, 3s2, 3p5
B) 1s2, 2s2, 2p6, 3s2, 3p6 D) 1s2, 2s2, 2p6, 3s2, 3p4
5. Which of the following statements about valence electrons is true?
A) They are the most tightly held electrons.
B) They do not participate in chemical reactions.
Page 3
, Chapter 1: Structure and Bonding
C) They sare sthe soutermost selectrons.
D) They sreveal sthe speriod snumber sof sa ssecond-row selement.
6. Which sof sthe sfollowing sstatements sabout sbonding sis strue?
A) Covalent sbonds sresult sfrom sthe stransfer sof selectrons sfrom sone selement sto s another.
B) Ionic sbonds sresult s from sthe stransfer sof selectrons sfrom sa smetal sto sa snon-metal.
C) Ionic sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo snon-metals.
D) Covalent sbonds sresult sfrom sthe ssharing sof selectrons sbetween stwo smetals.
7. Which sof sthe sfollowing swould syou sexpect s to shave sionic sbonds?
A) CO B) s sFBr C) s NF3 D) s sNaCl
8. Which sof sthe sfollowing s molecules shas snonpolar scovalent sbonds?
A) HCl B) s N2 C) s CHCl3 D) s sNO
9. Which sof sthe sfollowing s molecules scontain sboth scovalent s and sionic sbonds?
A) I, sII B) s sI, sIV C) s sII, sIII D) sII, sIV
10. Arrange sthe sfollowing sbonds sin sdecreasing sorder sof sionic scharacter, sputting sthe
smost s ionic s first.
A) I s> sII s> sIII s> sIV C) IV s> sIII s> sII s> sI
B) IV s> sII s> sI s> sIII D) IV s> sII s> sIII s> sI
11. Which sof sthe sfollowing sstatements scorrectly sdescribes sthe stypical snumber sof sbonds
sfor s carbon, snitrogen, sand soxygen sin smost s neutral sorganic smolecules?
A) Carbon sforms s4 scovalent s bonds, snitrogen sforms s2 scovalent sbonds sand soxygen
sforms s 3 scovalent s bonds.
B) Carbon sforms s4 scovalent s bonds, snitrogen sforms s3 scovalent sbonds sand soxygen
sforms s 2 scovalent s bonds.
Page 4
