Test bank organic chemistry mechanistic patterns 1st
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edition by Ghis w. Ogilvie nathan Ackroyd All
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Chapters 1-20 Covered
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Page
1
,TABLE OF CONTENT
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CHAPTER 1 Carbon and Its Compounds......Page 27
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CHAPTER 2 Anatomy of an Organic Molecule......Page 73
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CHAPTER 3 Molecules in Motion: Conformations by Rotations......Page 112
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CHAPTER 4 Stereochemistry: Three-Dimensional Structure in Molecules......Page 151
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CHAPTER 5 Organic Reaction Mechanism: Using Curved Arrows to Analyze Reaction Mechanisms......Page
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212
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CHAPTER 6 Acids and Bases......Page 261
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CHAPTER 7 π Bonds as Electrophiles: Reactions of Carbonyls and Related Functional Groups......Page 298
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CHAPTER 8 π Bonds as Nucleophiles: Reactions of Alkenes, Alkynes, Dienes, and Enols......Page 354
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CHAPTER 9 Conjugation and Aromaticity......Page 424
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CHAPTER 10 Synthesis Using Aromatic Materials: Electrophilic Aromatic Substitution and Directed Ortho
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Metalation......Page 457
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CHAPTER 11 Displacement Reactions on Saturated Carbons: SN1 and SN2 Substitution Reactions......Page
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520
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CHAPTER 12 Formation of π Bonds by Elimination Processes: Elimination and Oxidation Reactions......Page
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566
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CHAPTER 13 Structure Determination I: Nuclear Magnetic Resonance Spectroscopy......Page 603
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CHAPTER 14 Structure Determination II: Mass Spectrometry and Infrared Spectroscopy......Page 674
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CHAPTER 15 π Bond Electrophiles Connected to Leaving Groups: Carboxylic Acid Derivatives......Page 722
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CHAPTER 16 π Bonds with Hidden Leaving Groups: Reactions of Acetals and Related Compounds......Page
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790
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CHAPTER 17 Carbonyl-Based Nucleophiles: Aldol, Claisen, Wittig, and Related Enolate Reactions......Page
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836
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CHAPTER 18 Selectivity and Reactivity in Enolate Reactions: Control of Stereoselectivity and......Page 925
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CHAPTER 19 Radicals: Halogenation, Polymerization, and Reduction Reactions......Page 997
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CHAPTER 20 Reactions Controlled by Orbital Interaction
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Page
2
,Test Bank for oo oo
Organic Chemistry Mechanistic Patterns 1st Edition by Ogilvie, Ackroyd, Browning,
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Deslongchamps, Sauer ISBN 9780176702717
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Chapter 1-20 oo
CHAPTER 1 - Carbon and Its Compounds
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2-
1. Which of the following represents the ground state electron configuration for
oo oo oo oo oo oo oo oo oo oo ion?
a
oo o o O
a. 1s22s22p4
oo
b. 1s22s22p2
oo
c. 1s22s22p6
oo
d. 2s22p4
oo
ANSWER: c oo oo
2. How many valence electrons does a nitrogen atom contain?
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a. 2
b. 3
c. 5
d. 7
ANSWER: c oo oo
2-
3. How many valence electrons does anO ion contain?
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a. 2
b. 6
c. 8
d. 10
ANSWER: c oo oo
Page
3
, 4. What is the Lewis structure of a compound that has the formula of CCl3 and contains 24 valence
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electrons?
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a.
b.
c.
d.
ANSWER: d oo oo
5. How many bonded and non-bonded electrons does a molecule with no formal charges and the
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formula C2H4O2 contain?
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a. 4 bonded, 4 non-bonded
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b. 7 bonded. 4 non-bonded
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c. 7 bonded, 5 non-bonded
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d. 4 bonded, 7 non-bonded
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ANSWER: b oo oo
Figure 1 oo
6. Referring to Figure 1, what is the formal charge of the oxygen atom at I?
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a. +1 oo
b. 0
c. -1
d. -2
ANSWER: b oo oo
7. Referring to Figure 1, what is the formal charge of the oxygen atom at II?
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a. +1 oo
b. 0
c. -1
Page
4
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edition by Ghis w. Ogilvie nathan Ackroyd All
oo oo oo oo oo oo oo oo
Chapters 1-20 Covered
oo oo oo
Page
1
,TABLE OF CONTENT
oo oo
CHAPTER 1 Carbon and Its Compounds......Page 27
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CHAPTER 2 Anatomy of an Organic Molecule......Page 73
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CHAPTER 3 Molecules in Motion: Conformations by Rotations......Page 112
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CHAPTER 4 Stereochemistry: Three-Dimensional Structure in Molecules......Page 151
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CHAPTER 5 Organic Reaction Mechanism: Using Curved Arrows to Analyze Reaction Mechanisms......Page
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212
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CHAPTER 6 Acids and Bases......Page 261
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CHAPTER 7 π Bonds as Electrophiles: Reactions of Carbonyls and Related Functional Groups......Page 298
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CHAPTER 8 π Bonds as Nucleophiles: Reactions of Alkenes, Alkynes, Dienes, and Enols......Page 354
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CHAPTER 9 Conjugation and Aromaticity......Page 424
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CHAPTER 10 Synthesis Using Aromatic Materials: Electrophilic Aromatic Substitution and Directed Ortho
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Metalation......Page 457
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CHAPTER 11 Displacement Reactions on Saturated Carbons: SN1 and SN2 Substitution Reactions......Page
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520
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CHAPTER 12 Formation of π Bonds by Elimination Processes: Elimination and Oxidation Reactions......Page
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566
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CHAPTER 13 Structure Determination I: Nuclear Magnetic Resonance Spectroscopy......Page 603
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CHAPTER 14 Structure Determination II: Mass Spectrometry and Infrared Spectroscopy......Page 674
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CHAPTER 15 π Bond Electrophiles Connected to Leaving Groups: Carboxylic Acid Derivatives......Page 722
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CHAPTER 16 π Bonds with Hidden Leaving Groups: Reactions of Acetals and Related Compounds......Page
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790
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CHAPTER 17 Carbonyl-Based Nucleophiles: Aldol, Claisen, Wittig, and Related Enolate Reactions......Page
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836
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CHAPTER 18 Selectivity and Reactivity in Enolate Reactions: Control of Stereoselectivity and......Page 925
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CHAPTER 19 Radicals: Halogenation, Polymerization, and Reduction Reactions......Page 997
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CHAPTER 20 Reactions Controlled by Orbital Interaction
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Page
2
,Test Bank for oo oo
Organic Chemistry Mechanistic Patterns 1st Edition by Ogilvie, Ackroyd, Browning,
oo oo oo oo oo oo oo oo oo
Deslongchamps, Sauer ISBN 9780176702717
o o oo oo oo
Chapter 1-20 oo
CHAPTER 1 - Carbon and Its Compounds
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2-
1. Which of the following represents the ground state electron configuration for
oo oo oo oo oo oo oo oo oo oo ion?
a
oo o o O
a. 1s22s22p4
oo
b. 1s22s22p2
oo
c. 1s22s22p6
oo
d. 2s22p4
oo
ANSWER: c oo oo
2. How many valence electrons does a nitrogen atom contain?
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a. 2
b. 3
c. 5
d. 7
ANSWER: c oo oo
2-
3. How many valence electrons does anO ion contain?
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a. 2
b. 6
c. 8
d. 10
ANSWER: c oo oo
Page
3
, 4. What is the Lewis structure of a compound that has the formula of CCl3 and contains 24 valence
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electrons?
oo
a.
b.
c.
d.
ANSWER: d oo oo
5. How many bonded and non-bonded electrons does a molecule with no formal charges and the
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formula C2H4O2 contain?
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a. 4 bonded, 4 non-bonded
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b. 7 bonded. 4 non-bonded
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c. 7 bonded, 5 non-bonded
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d. 4 bonded, 7 non-bonded
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ANSWER: b oo oo
Figure 1 oo
6. Referring to Figure 1, what is the formal charge of the oxygen atom at I?
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a. +1 oo
b. 0
c. -1
d. -2
ANSWER: b oo oo
7. Referring to Figure 1, what is the formal charge of the oxygen atom at II?
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a. +1 oo
b. 0
c. -1
Page
4
