RE A l t l 0 N RAT E S i
RAT E Of CH t M l C A L R t A CT l O N i l H A N h t I N
C ONC E N T R AT l on Of RE ALT A N t l
P R OD U C t I N a lV E N T I M E
RA T C CHA C0NC
T I ME
UN I T s mold m 35
R AT E f AS T E S T AT S T AR T A S EAL H
RE A C T A NT RC O N C
S L O W S D O W N AS R EA C T AN T C O NC t
NH E N I R t n c t ANT c OM P L t i t l Y Us t D UP
CO NC S TO P S C H A Na I N a t R A T E 2 E RO
concentration res steep
molam
e STEEP PRATE
TIME IS
AL T E R A T I N G R A t t of C H t M l C AL r t A Ci l 0 N
C ON C 1 P R E S SV R E
T tmp
CAT A L Y S T
o S A O f S O L I D R EA L T A N T S
C O L I I S IO N TH E O R Y
L R E A C T I NG P Ah i l C l t s mU s t CO L L I D E
FO R R E A CT 1 O N T O O c c u R
O N LY SM A L L P RO P O R i l O N O f C O l l l s l 0NS
RE S U L t I N C H t m l l A L REA L t l ON
I N mo s T CO L l I s l O N S MO h s c O L L I D E BU t
BO V N C E of F E AC H O THE R SO R E MA l N
CHEM l l A l l Y U N l HA N a E D
WH Y S O ME CO L L i s I 0 NS I N E f f E C T I V E
, E f f t l i l v E COL l I S I ONS l t AD 1 O CHEM
REACTION
2 CON Dl ti ON S MET
part 1C L E S LO Ll I D t
Wi t H CORR C Lt
OR I t N tat l ON
P A R TI Ci t s sU f f I L I EN T ENERGY TO
Ov t R l OM t En
INE f f t c t I v t NO
REAL 1 I 0 N L Pur p l e
Mus t lo l Ll D t
c
NE Act 1 ON OCCURS
I N l R EAS l Na lo n c
A CONC O f R t A CT ANT p ROR
pl ON C MO R E P AR t l C l c s 1N SAME VOL
P A r t l C l t s c l O S ER t lo l l l D t MORE
f REQ U E N T LY
I N G I VE N t l ME Af R t au EN ly Ef f t CTI v E
C O L l I S I ONS
DEPENDENT ON S U f f l CI E N T E NE R GY t
CORR t C T O R I E NTA i l O N
I N CREA S I Na p ne s SURE
GAS COM P R t s s t D TO SMA L l C R V OL SO
PRESSURE RO R I N l R t As t
CO NC O f h Al MO IS P t S AME NO PARTICLES
OCCUPY S MA l I t R VOLUME
GAS MO LS CLOSER t C O LL I D E SU C C C S FULLY
MORE FREQUENTLY
MORE EFFECTIVE COLLISIONS IN SAME
TIME
IN CRE AS 1 Nh TEMP
A V E RA a t ht of P AR i l CI E S P
p pro P O Rtl O N of par T l C l t S HAV E ENERGY
RAT E Of CH t M l C A L R t A CT l O N i l H A N h t I N
C ONC E N T R AT l on Of RE ALT A N t l
P R OD U C t I N a lV E N T I M E
RA T C CHA C0NC
T I ME
UN I T s mold m 35
R AT E f AS T E S T AT S T AR T A S EAL H
RE A C T A NT RC O N C
S L O W S D O W N AS R EA C T AN T C O NC t
NH E N I R t n c t ANT c OM P L t i t l Y Us t D UP
CO NC S TO P S C H A Na I N a t R A T E 2 E RO
concentration res steep
molam
e STEEP PRATE
TIME IS
AL T E R A T I N G R A t t of C H t M l C AL r t A Ci l 0 N
C ON C 1 P R E S SV R E
T tmp
CAT A L Y S T
o S A O f S O L I D R EA L T A N T S
C O L I I S IO N TH E O R Y
L R E A C T I NG P Ah i l C l t s mU s t CO L L I D E
FO R R E A CT 1 O N T O O c c u R
O N LY SM A L L P RO P O R i l O N O f C O l l l s l 0NS
RE S U L t I N C H t m l l A L REA L t l ON
I N mo s T CO L l I s l O N S MO h s c O L L I D E BU t
BO V N C E of F E AC H O THE R SO R E MA l N
CHEM l l A l l Y U N l HA N a E D
WH Y S O ME CO L L i s I 0 NS I N E f f E C T I V E
, E f f t l i l v E COL l I S I ONS l t AD 1 O CHEM
REACTION
2 CON Dl ti ON S MET
part 1C L E S LO Ll I D t
Wi t H CORR C Lt
OR I t N tat l ON
P A R TI Ci t s sU f f I L I EN T ENERGY TO
Ov t R l OM t En
INE f f t c t I v t NO
REAL 1 I 0 N L Pur p l e
Mus t lo l Ll D t
c
NE Act 1 ON OCCURS
I N l R EAS l Na lo n c
A CONC O f R t A CT ANT p ROR
pl ON C MO R E P AR t l C l c s 1N SAME VOL
P A r t l C l t s c l O S ER t lo l l l D t MORE
f REQ U E N T LY
I N G I VE N t l ME Af R t au EN ly Ef f t CTI v E
C O L l I S I ONS
DEPENDENT ON S U f f l CI E N T E NE R GY t
CORR t C T O R I E NTA i l O N
I N CREA S I Na p ne s SURE
GAS COM P R t s s t D TO SMA L l C R V OL SO
PRESSURE RO R I N l R t As t
CO NC O f h Al MO IS P t S AME NO PARTICLES
OCCUPY S MA l I t R VOLUME
GAS MO LS CLOSER t C O LL I D E SU C C C S FULLY
MORE FREQUENTLY
MORE EFFECTIVE COLLISIONS IN SAME
TIME
IN CRE AS 1 Nh TEMP
A V E RA a t ht of P AR i l CI E S P
p pro P O Rtl O N of par T l C l t S HAV E ENERGY
