TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Pagev1
,Chapterv1vStructurevandvBonding
Chapterv2vAcidsvandvBases
Chapterv3vIntroductionvtovOrganicvMoleculesvandvFunctionalvGroups
Chapterv4vAlkanes
Chapterv5vStereochemistry
Chapterv6vUnderstandingvOrganicvReactions
Chapterv7vAlkylvHalidesvandvNucleophilicvSubstitution
Chapterv8vAlkylvHalidesvandvEliminationvReactions
Chapterv9vAlcohols,vEthers,vandvRelatedvCompounds
Chapterv10vAlkenesvandvAdditionvReactions
Chapterv11vAlkynesvandvSynthesis
Chapterv12vOxidationvandvReduction
SpectroscopyvAvMassvSpectrometry
SpectroscopyvBvInfraredvSpectroscopy
SpectroscopyvCvNuclearvMagneticvResonancevSpectroscopy
Chapterv13vRadicalvReactions
Chapterv14vConjugation,vResonance,vandvDienes
Chapterv15vBenzenevandvAromaticvCompounds
Chapterv16vReactionsvofvAromaticvCompounds
Chapterv17vIntroductionvtovCarbonylvChemistry:vOrganometallicvReagents;vOxid
ationvandvReduction
Chapterv18vAldehydesvandvKetones—NucleophilicvAddition
Chapterv19vCarboxylicvAcidsvandvNitriles
Chapterv20vCarboxylicvAcidsvandvTheirvDerivatives-
vNucleophilicvAcylvSubstitution
Chapterv21vSubstitutionvReactionsvofvCarbonylvCompoundsvatvthevα-Carbon
Chapterv22vCarbonylvCondensationvReactions
Chapterv23vAmines
Chapterv24vCarbon-CarbonvBond-FormingvReactionsvinvOrganicvSynthesis
Chapterv25vPericyclicvReactions
Chapterv26vCarbohydrates
Chapterv27vAminovAcidsvandvProteins
Chapterv28vSyntheticvPolymers
Chapterv29vLipidsv(Availablevonline)
Pagev2
, Chapter 1: Structure and Bonding
v v v v
1. Whatvisvthevground-
statevelectronicvconfigurationvofvavcarbonvatom?vA)v 1s2,v2s2,v2p5
B)v 1s2,v2s2,v2p2 C)v 1s2,v2s2,v2p6 D)v 1s2,v2s2,v2p4
2. Whatvisvthevground-
statevelectronicvconfigurationvofvavfluorinevatom?vA)v 1s2,v2s2,v2p2
B)v 1s2,v2s2,v2p3 C)v 1s2,v2s2,v2p4 D)v 1s2,v2s2,v2p5
3. Whatvisvthevground-
statevelectronicvconfigurationvofvavmagnesiumvcationv(Mg2+)?vA) 1s2,v2s2,v2p6
C) 1s2,v2s2,v2p6,v3s2
B) 1s2,v2s2,v2p6,v3s1 D) 1s2,v2s2,v2p6,v3s2,v3p2
4. Whatvisvthevground-statevelectronicvconfigurationvofvavchlorinevanionv(Cl—
)?vA) 1s2,v2s2,v2p6 C) 1s2,v2s2,v2p6,v3s2,v3p5
B) 1s2,v2s2,v2p6,v3s2,v3p6 D) 1s2,v2s2,v2p6,v3s2,v3p4
5. Whichvofvthevfollowingvstatementsvaboutvvalencevelectronsvisvtrue?
A) Theyvarevthevmostvtightlyvheldvelectrons.
B) Theyvdovnotvparticipatevinvchemicalvreactions.
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, Chapterv1:vStructurevandvBondin
g
C) Theyvarevthevoutermostvelectrons.
D) Theyvrevealvthevperiodvnumbervofvavsecond-rowvelement.
6. Whichvofvthevfollowingvstatementsvaboutvbondingvisvtrue?
A) Covalentvbondsvresultvfromvthevtransfervofvelectronsvfromvonevelementvtovanother.
B) Ionicvbondsvresultvfromvthevtransfervofvelectronsvfromvavmetalvtovavnon-metal.
C) Ionicvbondsvresultvfromvthevsharingvofvelectronsvbetweenvtwovnon-metals.
D) Covalentvbondsvresultvfromvthevsharingvofvelectronsvbetweenvtwovmetals.
7. Whichvofvthevfollowingvwouldvyouvexpectvtovhavevionicvbonds?
A) CO B)v FBr C)v NF3 D)v NaCl
8. Whichvofvthevfollowingvmoleculesvhasvnonpolarvcovalentvbonds?
A) HCl B)v N2 C)v CHCl3 D)v NO
9. Whichvofvthevfollowingvmoleculesvcontainvbothvcovalentvandvionicvbonds?
A) I,vII B)v I,vIV C)v II,vIII D)vII,vIV
10. Arrangevthevfollowingvbondsvinvdecreasingvordervofvionicvcharacter,vputtingvthevmostv
ionicvfirst.
A) Iv>vIIv>vIIIv>vIV C) IVv>vIIIv>vIIv>vI
B) IVv>vIIv>vIv>vIII D) IVv>vIIv>vIIIv>vI
11. Whichvofvthevfollowingvstatementsvcorrectlyvdescribesvthevtypicalvnumbervofvbondsvforv
carbon,vnitrogen,vandvoxygenvinvmostvneutralvorganicvmolecules?
A) Carbonvformsv4vcovalentvbonds,vnitrogenvformsv2vcovalentvbondsvandvoxygenvformsv
3vcovalentvbonds.
B) Carbonvformsv4vcovalentvbonds,vnitrogenvformsv3vcovalentvbondsvandvoxygenvformsv
2vcovalentvbonds.
Pagev4
Smith / All Chapters 1 - 29 / Full Complete
Pagev1
,Chapterv1vStructurevandvBonding
Chapterv2vAcidsvandvBases
Chapterv3vIntroductionvtovOrganicvMoleculesvandvFunctionalvGroups
Chapterv4vAlkanes
Chapterv5vStereochemistry
Chapterv6vUnderstandingvOrganicvReactions
Chapterv7vAlkylvHalidesvandvNucleophilicvSubstitution
Chapterv8vAlkylvHalidesvandvEliminationvReactions
Chapterv9vAlcohols,vEthers,vandvRelatedvCompounds
Chapterv10vAlkenesvandvAdditionvReactions
Chapterv11vAlkynesvandvSynthesis
Chapterv12vOxidationvandvReduction
SpectroscopyvAvMassvSpectrometry
SpectroscopyvBvInfraredvSpectroscopy
SpectroscopyvCvNuclearvMagneticvResonancevSpectroscopy
Chapterv13vRadicalvReactions
Chapterv14vConjugation,vResonance,vandvDienes
Chapterv15vBenzenevandvAromaticvCompounds
Chapterv16vReactionsvofvAromaticvCompounds
Chapterv17vIntroductionvtovCarbonylvChemistry:vOrganometallicvReagents;vOxid
ationvandvReduction
Chapterv18vAldehydesvandvKetones—NucleophilicvAddition
Chapterv19vCarboxylicvAcidsvandvNitriles
Chapterv20vCarboxylicvAcidsvandvTheirvDerivatives-
vNucleophilicvAcylvSubstitution
Chapterv21vSubstitutionvReactionsvofvCarbonylvCompoundsvatvthevα-Carbon
Chapterv22vCarbonylvCondensationvReactions
Chapterv23vAmines
Chapterv24vCarbon-CarbonvBond-FormingvReactionsvinvOrganicvSynthesis
Chapterv25vPericyclicvReactions
Chapterv26vCarbohydrates
Chapterv27vAminovAcidsvandvProteins
Chapterv28vSyntheticvPolymers
Chapterv29vLipidsv(Availablevonline)
Pagev2
, Chapter 1: Structure and Bonding
v v v v
1. Whatvisvthevground-
statevelectronicvconfigurationvofvavcarbonvatom?vA)v 1s2,v2s2,v2p5
B)v 1s2,v2s2,v2p2 C)v 1s2,v2s2,v2p6 D)v 1s2,v2s2,v2p4
2. Whatvisvthevground-
statevelectronicvconfigurationvofvavfluorinevatom?vA)v 1s2,v2s2,v2p2
B)v 1s2,v2s2,v2p3 C)v 1s2,v2s2,v2p4 D)v 1s2,v2s2,v2p5
3. Whatvisvthevground-
statevelectronicvconfigurationvofvavmagnesiumvcationv(Mg2+)?vA) 1s2,v2s2,v2p6
C) 1s2,v2s2,v2p6,v3s2
B) 1s2,v2s2,v2p6,v3s1 D) 1s2,v2s2,v2p6,v3s2,v3p2
4. Whatvisvthevground-statevelectronicvconfigurationvofvavchlorinevanionv(Cl—
)?vA) 1s2,v2s2,v2p6 C) 1s2,v2s2,v2p6,v3s2,v3p5
B) 1s2,v2s2,v2p6,v3s2,v3p6 D) 1s2,v2s2,v2p6,v3s2,v3p4
5. Whichvofvthevfollowingvstatementsvaboutvvalencevelectronsvisvtrue?
A) Theyvarevthevmostvtightlyvheldvelectrons.
B) Theyvdovnotvparticipatevinvchemicalvreactions.
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, Chapterv1:vStructurevandvBondin
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C) Theyvarevthevoutermostvelectrons.
D) Theyvrevealvthevperiodvnumbervofvavsecond-rowvelement.
6. Whichvofvthevfollowingvstatementsvaboutvbondingvisvtrue?
A) Covalentvbondsvresultvfromvthevtransfervofvelectronsvfromvonevelementvtovanother.
B) Ionicvbondsvresultvfromvthevtransfervofvelectronsvfromvavmetalvtovavnon-metal.
C) Ionicvbondsvresultvfromvthevsharingvofvelectronsvbetweenvtwovnon-metals.
D) Covalentvbondsvresultvfromvthevsharingvofvelectronsvbetweenvtwovmetals.
7. Whichvofvthevfollowingvwouldvyouvexpectvtovhavevionicvbonds?
A) CO B)v FBr C)v NF3 D)v NaCl
8. Whichvofvthevfollowingvmoleculesvhasvnonpolarvcovalentvbonds?
A) HCl B)v N2 C)v CHCl3 D)v NO
9. Whichvofvthevfollowingvmoleculesvcontainvbothvcovalentvandvionicvbonds?
A) I,vII B)v I,vIV C)v II,vIII D)vII,vIV
10. Arrangevthevfollowingvbondsvinvdecreasingvordervofvionicvcharacter,vputtingvthevmostv
ionicvfirst.
A) Iv>vIIv>vIIIv>vIV C) IVv>vIIIv>vIIv>vI
B) IVv>vIIv>vIv>vIII D) IVv>vIIv>vIIIv>vI
11. Whichvofvthevfollowingvstatementsvcorrectlyvdescribesvthevtypicalvnumbervofvbondsvforv
carbon,vnitrogen,vandvoxygenvinvmostvneutralvorganicvmolecules?
A) Carbonvformsv4vcovalentvbonds,vnitrogenvformsv2vcovalentvbondsvandvoxygenvformsv
3vcovalentvbonds.
B) Carbonvformsv4vcovalentvbonds,vnitrogenvformsv3vcovalentvbondsvandvoxygenvformsv
2vcovalentvbonds.
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