CHM 2211C Lesson '0: Carboxylic Acids e+
1. Provide a complete IUPAC name for each of the following compounds. Be certain to include stereochemical
designations as appropriate
) /\/Y\n/ OH
)J\(W/
liar OH O
NH2
o ¢ f) s
OH
OH
0
@
Y a " Bur g\ eranocic acid
o )] (=D -2 2 - Q.M\no_fl-me‘\'hn\Pefl*Molc
acigd
< Y (3=, 5D =
B -Bromo- 3-Vydroayep bamoie ncid
dd Y- Svetlovenyl - 1-e¥h~a\h¢¢mnocc [- R
e) &,3-dicnlers =Yoo buranoic acid
<) Cyclop eniq\l mednanaic acid
2. Assign the numbers 1-3 to the compounds in each of the following sets to indicate increasing acidity (most
acid = 3, least acidic = 1). A¥ir iy Yo \ote W+
a)
0 -
/\Hkon /><J\OH /\)J\OH
@ @ mMmosad acidic
M2 qroups are e- Am@hn% - Skrengihen Lorde ond weoken Gcidy
, 3. For each of the following reactions place the structure of the major organic product in the box provided.
Each numbered reagent set above (or below) the arrow represents a completely separate reaction, for these
multistep reactions place only the structure of the final product in the box. If the product is ionic, place
both the cation and the anion in the box.
a)
JY
OH NaOH
- T r of™?
b)
0 o
o NaH - ©/u\ o®
Noz
NO,
c)
o CH;MgBr - o ®
Ho)J\)\/k/ /\/\/\ \/
o
d)
(Y e
o
Br 1) Mg; THF @)K R
3) H;0" quuemas,
e)
i H,SO, ow
S\rv-ons
Oxididper
f)
X
1) BH, _ o\
W 2) H,0,; OF /W/\r \L[
3) HNO;; A
Shrong
Oxidiyper
oy
1. Provide a complete IUPAC name for each of the following compounds. Be certain to include stereochemical
designations as appropriate
) /\/Y\n/ OH
)J\(W/
liar OH O
NH2
o ¢ f) s
OH
OH
0
@
Y a " Bur g\ eranocic acid
o )] (=D -2 2 - Q.M\no_fl-me‘\'hn\Pefl*Molc
acigd
< Y (3=, 5D =
B -Bromo- 3-Vydroayep bamoie ncid
dd Y- Svetlovenyl - 1-e¥h~a\h¢¢mnocc [- R
e) &,3-dicnlers =Yoo buranoic acid
<) Cyclop eniq\l mednanaic acid
2. Assign the numbers 1-3 to the compounds in each of the following sets to indicate increasing acidity (most
acid = 3, least acidic = 1). A¥ir iy Yo \ote W+
a)
0 -
/\Hkon /><J\OH /\)J\OH
@ @ mMmosad acidic
M2 qroups are e- Am@hn% - Skrengihen Lorde ond weoken Gcidy
, 3. For each of the following reactions place the structure of the major organic product in the box provided.
Each numbered reagent set above (or below) the arrow represents a completely separate reaction, for these
multistep reactions place only the structure of the final product in the box. If the product is ionic, place
both the cation and the anion in the box.
a)
JY
OH NaOH
- T r of™?
b)
0 o
o NaH - ©/u\ o®
Noz
NO,
c)
o CH;MgBr - o ®
Ho)J\)\/k/ /\/\/\ \/
o
d)
(Y e
o
Br 1) Mg; THF @)K R
3) H;0" quuemas,
e)
i H,SO, ow
S\rv-ons
Oxididper
f)
X
1) BH, _ o\
W 2) H,0,; OF /W/\r \L[
3) HNO;; A
Shrong
Oxidiyper
oy
