TEST BANK for Organic Chemistry 6th Edition
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gg Smith / All Chapters 1 - 29 / Full Complete
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Page
1
,Chapter 1 Structure and Bonding
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Chapter 2 Acids and Bases
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Chapter 3 Introduction to Organic Molecules and Functional Groups
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Chapter 4 Alkanes
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Chapter 5 Stereochemistry
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Chapter 6 Understanding Organic Reactions
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Chapter 7 Alkyl Halides and Nucleophilic Substitution
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Chapter 8 Alkyl Halides and Elimination Reactions
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Chapter 9 Alcohols, Ethers, and Related Compounds
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Chapter 10 Alkenes and Addition Reactions
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Chapter 11 Alkynes and Synthesis
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Chapter 12 Oxidation and Reduction
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Spectroscopy A Mass Spectrometry
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Spectroscopy B Infrared Spectroscopy
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Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
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Chapter 13 Radical Reactions
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Chapter 14 Conjugation, Resonance, and Dienes
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Chapter 15 Benzene and Aromatic Compounds
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Chapter 16 Reactions of Aromatic Compounds
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Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
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Oxidation and Reduction
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Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
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Chapter 19 Carboxylic Acids and Nitriles
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Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
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Substitution
gg
Chapter 21
gg Substitution Reactions of Carbonyl Compounds at the α-Carbon
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Chapter 22
gg Carbonyl Condensation Reactions
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Chapter 23
gg Amines
gg
Chapter 24
gg Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
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Chapter 25
gg Pericyclic Reactions
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Chapter 26
gg Carbohydrates
gg
Chapter 27
gg Amino Acids and Proteins
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Chapter 28
gg Synthetic Polymers
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Chapter 29
gg Lipids (Available online)
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Page
2
, Chapter 1: Structure and Bonding
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1. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggcarbon
2 2 5
ggatom? ggA) g g 1s , gg2s , gg2p B) g g 1s2, gg2s2, gg2p2 C) g g 1s2,
2 6
gg2s , gg2p D) g g 1s2, gg2s2, gg2p4
2. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggfluorine
ggatom?g A) g g 1s2, gg2s2, gg2p2 B) g g 1s2, gg2s2, gg2p3 C) g g 1s2,
2 4 2 2 5
gg2s , gg2p D) g g 1s , gg2s , gg2p
3. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggmagnesium ggcation
2+
gg(Mg )?gA) 1s2, gg2s2, gg2p6 C) 1s2, gg2s2,
6 2
gg2p , gg3s
B) 1s2, gg2s2, gg2p6, gg3s1 D) 1s2, gg2s2, gg2p6, gg3s2, gg3p2
4. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggchlorine gganion
—
gg(Cl )?gA) 1s2, gg2s2, gg2p6 C)
2 2 6 2 5
1s , gg2s , gg2p , gg3s , gg3p
B) 1s2, gg2s2, gg2p6, gg3s2, gg3p6 D) 1s2, gg2s2, gg2p6, gg3s2, gg3p4
5. Which ggof ggthe ggfollowing ggstatements ggabout ggvalence ggelectrons ggis ggtrue?
A) They ggare ggthe ggmost ggtightly ggheld ggelectrons.
B) They ggdo ggnot ggparticipate ggin ggchemical ggreactions.
Page
3
, Chapter gg1: ggStructure ggand
ggBonding
C) They ggare ggthe ggoutermost ggelectrons.
D) They ggreveal ggthe ggperiod ggnumber ggof gga ggsecond-row ggelement.
6. Which ggof ggthe ggfollowing ggstatements ggabout ggbonding ggis ggtrue?
A) Covalent ggbonds ggresult ggfrom ggthe ggtransfer ggof ggelectrons ggfrom ggone ggelement ggto
gganother.
B) Ionic ggbonds ggresult ggfrom ggthe ggtransfer ggof ggelectrons ggfrom gga ggmetal ggto gga ggnon-metal.
C) Ionic ggbonds ggresult ggfrom ggthe ggsharing ggof ggelectrons ggbetween ggtwo ggnon-metals.
D) Covalent ggbonds ggresult ggfrom ggthe ggsharing ggof ggelectrons ggbetween ggtwo ggmetals.
7. Which ggof ggthe ggfollowing ggwould ggyou ggexpect ggto gghave ggionic ggbonds?
A) CO B) g g FBr C) g g NF3 D) g g NaCl
8. Which ggof ggthe ggfollowing ggmolecules gghas ggnonpolar ggcovalent ggbonds?
A) HCl B) g g N2 C) g g CHCl3 D) g g NO
9. Which ggof ggthe ggfollowing ggmolecules ggcontain ggboth ggcovalent ggand ggionic ggbonds?
A) I, ggII B) g g I, ggIV C) g g II, ggIII D) ggII, ggIV
10. Arrange ggthe ggfollowing ggbonds ggin ggdecreasing ggorder ggof ggionic ggcharacter, ggputting
ggthe ggmostg
ionic ggfirst.
A) I gg> ggII gg> ggIII gg> ggIV C) IV gg> ggIII gg> ggII gg> ggI
B) IV gg> ggII gg> ggI gg> ggIII D) IV gg> ggII gg> ggIII gg> ggI
11. Which ggof ggthe ggfollowing ggstatements ggcorrectly ggdescribes ggthe ggtypical ggnumber ggof
ggbonds ggforg
carbon, ggnitrogen, ggand ggoxygen ggin ggmost ggneutral ggorganic ggmolecules?
A) Carbon ggforms gg4 ggcovalent ggbonds, ggnitrogen ggforms gg2 ggcovalent ggbonds ggand
ggoxygen ggformsg 3 ggcovalent ggbonds.
B) Carbon ggforms gg4 ggcovalent ggbonds, ggnitrogen ggforms gg3 ggcovalent ggbonds ggand
ggoxygen ggformsg 2 ggcovalent ggbonds.
Page gg4
gg gg gg gg gg gg
gg Smith / All Chapters 1 - 29 / Full Complete
gg gg gg gg gg gg gg gg gg
Page
1
,Chapter 1 Structure and Bonding
gg gg gg gg
Chapter 2 Acids and Bases
gg gg gg gg
Chapter 3 Introduction to Organic Molecules and Functional Groups
gg gg gg gg gg gg gg gg
Chapter 4 Alkanes
gg gg
Chapter 5 Stereochemistry
gg gg
Chapter 6 Understanding Organic Reactions
gg gg gg gg
Chapter 7 Alkyl Halides and Nucleophilic Substitution
gg gg gg gg gg gg
Chapter 8 Alkyl Halides and Elimination Reactions
gg gg gg gg gg gg
Chapter 9 Alcohols, Ethers, and Related Compounds
gg gg gg gg gg gg
Chapter 10 Alkenes and Addition Reactions
gg gg gg gg gg
Chapter 11 Alkynes and Synthesis
gg gg gg gg
Chapter 12 Oxidation and Reduction
gg gg gg gg
Spectroscopy A Mass Spectrometry
gg gg gg
Spectroscopy B Infrared Spectroscopy
gg gg gg
Spectroscopy C Nuclear Magnetic Resonance Spectroscopy
gg gg gg gg gg
Chapter 13 Radical Reactions
gg gg gg
Chapter 14 Conjugation, Resonance, and Dienes
gg gg gg gg gg
Chapter 15 Benzene and Aromatic Compounds
gg gg gg gg gg
Chapter 16 Reactions of Aromatic Compounds
gg gg gg gg gg
Chapter 17 Introduction to Carbonyl Chemistry: Organometallic Reagents;
gg gg gg gg gg gg gg
Oxidation and Reduction
gg gg gg
Chapter 18 Aldehydes and Ketones—Nucleophilic Addition
gg gg gg gg gg
Chapter 19 Carboxylic Acids and Nitriles
gg gg gg gg gg
Chapter 20 Carboxylic Acids and Their Derivatives- Nucleophilic Acyl
gg gg gg gg gg gg gg gg
Substitution
gg
Chapter 21
gg Substitution Reactions of Carbonyl Compounds at the α-Carbon
gg gg gg gg gg gg gg gg
Chapter 22
gg Carbonyl Condensation Reactions
gg gg gg
Chapter 23
gg Amines
gg
Chapter 24
gg Carbon-Carbon Bond-Forming Reactions in Organic Synthesis
gg gg gg gg gg gg
Chapter 25
gg Pericyclic Reactions
gg gg
Chapter 26
gg Carbohydrates
gg
Chapter 27
gg Amino Acids and Proteins
gg gg gg gg
Chapter 28
gg Synthetic Polymers
gg gg
Chapter 29
gg Lipids (Available online)
gg gg gg
Page
2
, Chapter 1: Structure and Bonding
gg gg gg gg
1. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggcarbon
2 2 5
ggatom? ggA) g g 1s , gg2s , gg2p B) g g 1s2, gg2s2, gg2p2 C) g g 1s2,
2 6
gg2s , gg2p D) g g 1s2, gg2s2, gg2p4
2. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggfluorine
ggatom?g A) g g 1s2, gg2s2, gg2p2 B) g g 1s2, gg2s2, gg2p3 C) g g 1s2,
2 4 2 2 5
gg2s , gg2p D) g g 1s , gg2s , gg2p
3. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggmagnesium ggcation
2+
gg(Mg )?gA) 1s2, gg2s2, gg2p6 C) 1s2, gg2s2,
6 2
gg2p , gg3s
B) 1s2, gg2s2, gg2p6, gg3s1 D) 1s2, gg2s2, gg2p6, gg3s2, gg3p2
4. What ggis ggthe ggground-state ggelectronic ggconfiguration ggof gga ggchlorine gganion
—
gg(Cl )?gA) 1s2, gg2s2, gg2p6 C)
2 2 6 2 5
1s , gg2s , gg2p , gg3s , gg3p
B) 1s2, gg2s2, gg2p6, gg3s2, gg3p6 D) 1s2, gg2s2, gg2p6, gg3s2, gg3p4
5. Which ggof ggthe ggfollowing ggstatements ggabout ggvalence ggelectrons ggis ggtrue?
A) They ggare ggthe ggmost ggtightly ggheld ggelectrons.
B) They ggdo ggnot ggparticipate ggin ggchemical ggreactions.
Page
3
, Chapter gg1: ggStructure ggand
ggBonding
C) They ggare ggthe ggoutermost ggelectrons.
D) They ggreveal ggthe ggperiod ggnumber ggof gga ggsecond-row ggelement.
6. Which ggof ggthe ggfollowing ggstatements ggabout ggbonding ggis ggtrue?
A) Covalent ggbonds ggresult ggfrom ggthe ggtransfer ggof ggelectrons ggfrom ggone ggelement ggto
gganother.
B) Ionic ggbonds ggresult ggfrom ggthe ggtransfer ggof ggelectrons ggfrom gga ggmetal ggto gga ggnon-metal.
C) Ionic ggbonds ggresult ggfrom ggthe ggsharing ggof ggelectrons ggbetween ggtwo ggnon-metals.
D) Covalent ggbonds ggresult ggfrom ggthe ggsharing ggof ggelectrons ggbetween ggtwo ggmetals.
7. Which ggof ggthe ggfollowing ggwould ggyou ggexpect ggto gghave ggionic ggbonds?
A) CO B) g g FBr C) g g NF3 D) g g NaCl
8. Which ggof ggthe ggfollowing ggmolecules gghas ggnonpolar ggcovalent ggbonds?
A) HCl B) g g N2 C) g g CHCl3 D) g g NO
9. Which ggof ggthe ggfollowing ggmolecules ggcontain ggboth ggcovalent ggand ggionic ggbonds?
A) I, ggII B) g g I, ggIV C) g g II, ggIII D) ggII, ggIV
10. Arrange ggthe ggfollowing ggbonds ggin ggdecreasing ggorder ggof ggionic ggcharacter, ggputting
ggthe ggmostg
ionic ggfirst.
A) I gg> ggII gg> ggIII gg> ggIV C) IV gg> ggIII gg> ggII gg> ggI
B) IV gg> ggII gg> ggI gg> ggIII D) IV gg> ggII gg> ggIII gg> ggI
11. Which ggof ggthe ggfollowing ggstatements ggcorrectly ggdescribes ggthe ggtypical ggnumber ggof
ggbonds ggforg
carbon, ggnitrogen, ggand ggoxygen ggin ggmost ggneutral ggorganic ggmolecules?
A) Carbon ggforms gg4 ggcovalent ggbonds, ggnitrogen ggforms gg2 ggcovalent ggbonds ggand
ggoxygen ggformsg 3 ggcovalent ggbonds.
B) Carbon ggforms gg4 ggcovalent ggbonds, ggnitrogen ggforms gg3 ggcovalent ggbonds ggand
ggoxygen ggformsg 2 ggcovalent ggbonds.
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