AQA A-LEVEL CHEMISTRY PAPER 3 CGP PRACTICE TEST FF
I2m+mCH3COCH3m-->mCH3COCH2Im+mH+m+mI-m
Suggestmthemtypemofmreactionmthatmoccursmwhenmpropanonemreactsmwithmiodineminmanm
acidicmsolution.m-m"ACCURATEmANSWER"mmsubstitution
Explainmwhymthemscientistmchosemconcentrationsmofmpropanonemandmhydrochloricmacidmtha
tmweremmuchmgreatermthanmthatmofmiodinemsolution.m-
m"ACCURATEmANSWER"mmSomthatmratemwillmonlymdependmonmiodine
Describemexperimentsmusingmtheminitialmratesmmethodmtomdeterminemthatmthismreaction'sm
reactantm(x)misminmsecondmorder.mx9m-m"ACCURATEmANSWER"mm1-
mcarrymoutmthemexperimentsmseveralmtimesmatmdifferentmconcentrationsmofmxm
2-mkeepmthemconcentrationmofmthemothermreactantsmconstant
3-mstartmthemtimermasmsoonmasmthemreactantsmaremmixed
4-mmeasuremthemconcentrationmofmXmasmregularmintervalsm
5-mplotmamgraphmofmXmconcentrationm(y-axis)mandmtimem(x-axis)
6-mdrawmcurvemofmbestmfitm
7-mdrawmthemtangentmatmt=0
8-mfindmthemgradientm=minitialmratem(formallmconcentrations)
9-
mcomparemthemconcentrationmandmtheminitialmratesm(e.gmifmthemconc.mdoublesmandmthem
ratemquadruples)
I2m+mCH3COCH3m-->mCH3COCH2Im+mH+m+mI-m
Suggestmthemtypemofmreactionmthatmoccursmwhenmpropanonemreactsmwithmiodineminmanm
acidicmsolution.m-m"ACCURATEmANSWER"mmsubstitution
Explainmwhymthemscientistmchosemconcentrationsmofmpropanonemandmhydrochloricmacidmtha
tmweremmuchmgreatermthanmthatmofmiodinemsolution.m-
m"ACCURATEmANSWER"mmSomthatmratemwillmonlymdependmonmiodine
Describemexperimentsmusingmtheminitialmratesmmethodmtomdeterminemthatmthismreaction'sm
reactantm(x)misminmsecondmorder.mx9m-m"ACCURATEmANSWER"mm1-
mcarrymoutmthemexperimentsmseveralmtimesmatmdifferentmconcentrationsmofmxm
2-mkeepmthemconcentrationmofmthemothermreactantsmconstant
3-mstartmthemtimermasmsoonmasmthemreactantsmaremmixed
4-mmeasuremthemconcentrationmofmXmasmregularmintervalsm
5-mplotmamgraphmofmXmconcentrationm(y-axis)mandmtimem(x-axis)
6-mdrawmcurvemofmbestmfitm
7-mdrawmthemtangentmatmt=0
8-mfindmthemgradientm=minitialmratem(formallmconcentrations)
9-
mcomparemthemconcentrationmandmtheminitialmratesm(e.gmifmthemconc.mdoublesmandmthem
ratemquadruples)