TEST BANK for Organic Chemistry 6th Edition
Smith / All Chapters 1 - 29 / Full Complete
Pagea 1
,Chaptera1aStructureaandaBondingaChapte
ra2aAcidsaandaBases
Chaptera3aIntroductionatoaOrganicaMoleculesaandaFunctionalaGroupsaChaptera4a
Alkanes
Chaptera5aStereochemistry
Chaptera6aUnderstandingaOrganicaReactions
Chaptera7aAlkylaHalidesaandaNucleophilicaSubstitutionaChapt
era8aAlkylaHalidesaandaEliminationaReactionsaChaptera9aAlco
hols,aEthers,aandaRelatedaCompoundsaChaptera10aAlkenesaa
ndaAdditionaReactions
Chaptera11aAlkynesaandaSynthesisaChapt
era12aOxidationaandaReductionaSpectros
copyaAaMassaSpectrometryaSpectroscop
yaBaInfraredaSpectroscopy
SpectroscopyaCaNuclearaMagneticaResonanceaSpectroscopyaC
haptera13aRadicalaReactions
Chaptera14aConjugation,aResonance,aandaDienesaChapte
ra15aBenzeneaandaAromaticaCompoundsaChaptera16aReac
tionsaofaAromaticaCompounds
Chaptera17aIntroductionatoaCarbonylaChemistry:aOrganometallicaReagents;aOxiadati
onaandaReduction
Chaptera18aAldehydesaandaKetones—
NucleophilicaAdditionaChaptera19aCarboxylicaAcidsaandaNitrile
s
Chaptera20aCarboxylicaAcidsaandaTheiraDerivatives-
aNucleophilicaAcylaSubstitution
Chaptera21aSubstitutionaReactionsaofaCarbonylaCompoundsaatatheaα-
CarbonaChaptera22aCarbonylaCondensationaReactions
Chaptera23aAmines
Chaptera24aCarbon-CarbonaBond-
FormingaReactionsainaOrganicaSynthesisaChaptera25aPericyclicaReactions
Chaptera26aCarbohydrates
Chaptera27aAminoaAcidsaandaProteinsaCh
aptera28aSyntheticaPolymersaChaptera29
aLipidsa(Availableaonline)
Pagea 2
, Chapter 1: Structure and Bonding
C C C C
1. Whata isa thea ground-
statea electronica configurationa ofa aa carbona atom?a A)a 1s2,a 2s2,a 2p5
B) 1s2,a 2s2,a 2p2a a C)a 1s2,a 2s2,a 2p6a a D)a 1s2,a 2s2,a 2p4
2. Whata isa thea ground-
statea electronica configurationa ofa aa fluorinea atom?aA)a 1s2,a 2s2,a 2p2
B) 1s2,a 2s2,a 2p3a a C)a 1s2,a 2s2,a 2p4a a D)a 1s2,a 2s2,a 2p5
3. Whata isa thea ground-
stateaelectronicaconfigurationaofaaamagnesiumacationa(Mg2+)?aA)a1s2
,a2s2,a2p6 C) 1s2,a2s2,a2p6,a3s2
B) 1s2,a 2s2,a 2p6,a 3s1 D) 1s2,a 2s2,a 2p6,a 3s2,a 3p2
4. Whata isa thea ground-statea electronica configurationa ofa aa chlorinea aniona (Cl—
)?aA)1s2,a 2s2,a 2p6 C) 1s2,a 2s2,a 2p6,a 3s2,a 3p5
B) 1s2,a 2s2,a 2p6,a 3s2,a 3p6 D) 1s2,a 2s2,a 2p6,a 3s2,a 3p4
5. Whicha ofa thea followinga statementsa abouta valencea electronsa isa true?
A) Theya area thea mosta tightlya helda electrons.
B) Theya doa nota participatea ina chemicala reactions.
Pagea 3
, Chaptera 1:a Structurea anda Bondin
C) Theya area thea outermosta electrons.
D) Theya reveala thea perioda numbera ofa aa second-rowa element.
6. Whicha ofa thea followinga statementsa abouta bondinga isa true?
A) Covalenta bondsa resulta froma thea transfera ofa electronsa froma onea elementa toa another.
B) Ionica bondsa resulta froma thea transferCofa electronsa froma aa metala toa aa non-metal.
C) Ionica bondsa resulta froma thea sharinga ofa electronsa betweena twoa non-metals.
D) Covalenta bondsa resulta froma thea sharinga ofa electronsa betweena twoa metals.
7. Whicha ofa thea followinga woulda youa expecta toa havea ionica bonds?
A)a CO B)a FBr C)a NF3 D)a NaCl
8. Whicha ofa thea followinga moleculesa hasa nonpolara covalenta bonds?
A)a HCl B)a N2 C)a CHCl3 D)a NO
9. Whicha ofa thea followinga moleculesa containa botha covalenta anda ionica bonds?
A)a I,a II B)a I,a IVa a C)a II,a III D)a II,a IV
10. Arrangeatheafollowingabondsainadecreasingaorderaofaionicacharacter,aputtingatheamaosti
onicafirst.
A) Ia >a IIa >a IIIa >a IV C) IVa >a IIIa >a IIa >a I
B) IVa >a IIa >a Ia >a III D) IVa >a IIa >a IIIa >a I
11. Whichaofatheafollowingastatementsacorrectlyadescribesatheatypicalanumberaofabondsafor
carbon,anitrogen,aandaoxygenainamostaneutrala organicamolecules?
A) Carbonaformsa4acovalentabonds,anitrogenaformsa2acovalentabondsaandaoxygenaforamsa
3acovalentabonds.
B) Carbonaformsa4acovalentabonds,anitrogenaformsa3acovalentabondsaandaoxygenaforamsa
2acovalentabonds.
Pagea 4
Smith / All Chapters 1 - 29 / Full Complete
Pagea 1
,Chaptera1aStructureaandaBondingaChapte
ra2aAcidsaandaBases
Chaptera3aIntroductionatoaOrganicaMoleculesaandaFunctionalaGroupsaChaptera4a
Alkanes
Chaptera5aStereochemistry
Chaptera6aUnderstandingaOrganicaReactions
Chaptera7aAlkylaHalidesaandaNucleophilicaSubstitutionaChapt
era8aAlkylaHalidesaandaEliminationaReactionsaChaptera9aAlco
hols,aEthers,aandaRelatedaCompoundsaChaptera10aAlkenesaa
ndaAdditionaReactions
Chaptera11aAlkynesaandaSynthesisaChapt
era12aOxidationaandaReductionaSpectros
copyaAaMassaSpectrometryaSpectroscop
yaBaInfraredaSpectroscopy
SpectroscopyaCaNuclearaMagneticaResonanceaSpectroscopyaC
haptera13aRadicalaReactions
Chaptera14aConjugation,aResonance,aandaDienesaChapte
ra15aBenzeneaandaAromaticaCompoundsaChaptera16aReac
tionsaofaAromaticaCompounds
Chaptera17aIntroductionatoaCarbonylaChemistry:aOrganometallicaReagents;aOxiadati
onaandaReduction
Chaptera18aAldehydesaandaKetones—
NucleophilicaAdditionaChaptera19aCarboxylicaAcidsaandaNitrile
s
Chaptera20aCarboxylicaAcidsaandaTheiraDerivatives-
aNucleophilicaAcylaSubstitution
Chaptera21aSubstitutionaReactionsaofaCarbonylaCompoundsaatatheaα-
CarbonaChaptera22aCarbonylaCondensationaReactions
Chaptera23aAmines
Chaptera24aCarbon-CarbonaBond-
FormingaReactionsainaOrganicaSynthesisaChaptera25aPericyclicaReactions
Chaptera26aCarbohydrates
Chaptera27aAminoaAcidsaandaProteinsaCh
aptera28aSyntheticaPolymersaChaptera29
aLipidsa(Availableaonline)
Pagea 2
, Chapter 1: Structure and Bonding
C C C C
1. Whata isa thea ground-
statea electronica configurationa ofa aa carbona atom?a A)a 1s2,a 2s2,a 2p5
B) 1s2,a 2s2,a 2p2a a C)a 1s2,a 2s2,a 2p6a a D)a 1s2,a 2s2,a 2p4
2. Whata isa thea ground-
statea electronica configurationa ofa aa fluorinea atom?aA)a 1s2,a 2s2,a 2p2
B) 1s2,a 2s2,a 2p3a a C)a 1s2,a 2s2,a 2p4a a D)a 1s2,a 2s2,a 2p5
3. Whata isa thea ground-
stateaelectronicaconfigurationaofaaamagnesiumacationa(Mg2+)?aA)a1s2
,a2s2,a2p6 C) 1s2,a2s2,a2p6,a3s2
B) 1s2,a 2s2,a 2p6,a 3s1 D) 1s2,a 2s2,a 2p6,a 3s2,a 3p2
4. Whata isa thea ground-statea electronica configurationa ofa aa chlorinea aniona (Cl—
)?aA)1s2,a 2s2,a 2p6 C) 1s2,a 2s2,a 2p6,a 3s2,a 3p5
B) 1s2,a 2s2,a 2p6,a 3s2,a 3p6 D) 1s2,a 2s2,a 2p6,a 3s2,a 3p4
5. Whicha ofa thea followinga statementsa abouta valencea electronsa isa true?
A) Theya area thea mosta tightlya helda electrons.
B) Theya doa nota participatea ina chemicala reactions.
Pagea 3
, Chaptera 1:a Structurea anda Bondin
C) Theya area thea outermosta electrons.
D) Theya reveala thea perioda numbera ofa aa second-rowa element.
6. Whicha ofa thea followinga statementsa abouta bondinga isa true?
A) Covalenta bondsa resulta froma thea transfera ofa electronsa froma onea elementa toa another.
B) Ionica bondsa resulta froma thea transferCofa electronsa froma aa metala toa aa non-metal.
C) Ionica bondsa resulta froma thea sharinga ofa electronsa betweena twoa non-metals.
D) Covalenta bondsa resulta froma thea sharinga ofa electronsa betweena twoa metals.
7. Whicha ofa thea followinga woulda youa expecta toa havea ionica bonds?
A)a CO B)a FBr C)a NF3 D)a NaCl
8. Whicha ofa thea followinga moleculesa hasa nonpolara covalenta bonds?
A)a HCl B)a N2 C)a CHCl3 D)a NO
9. Whicha ofa thea followinga moleculesa containa botha covalenta anda ionica bonds?
A)a I,a II B)a I,a IVa a C)a II,a III D)a II,a IV
10. Arrangeatheafollowingabondsainadecreasingaorderaofaionicacharacter,aputtingatheamaosti
onicafirst.
A) Ia >a IIa >a IIIa >a IV C) IVa >a IIIa >a IIa >a I
B) IVa >a IIa >a Ia >a III D) IVa >a IIa >a IIIa >a I
11. Whichaofatheafollowingastatementsacorrectlyadescribesatheatypicalanumberaofabondsafor
carbon,anitrogen,aandaoxygenainamostaneutrala organicamolecules?
A) Carbonaformsa4acovalentabonds,anitrogenaformsa2acovalentabondsaandaoxygenaforamsa
3acovalentabonds.
B) Carbonaformsa4acovalentabonds,anitrogenaformsa3acovalentabondsaandaoxygenaforamsa
2acovalentabonds.
Pagea 4
