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Chapter 1: Structure and Bonding
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1. What jisjthejground-statejelectronicjconfigurationjof jajcarbonjatom?
A) 1s2 ,j2s2 ,j2p5 B)j 1s2 ,j2s2 ,j2p2 C)j 1s2 ,j2s2 ,j2p6 D)j 1s2 ,j2s2 ,j2p4
2. What jisjthejground-statejelectronicjconfigurationjof jajfluorinejatom?
A) 1s2 ,j2s2 ,j2p2 B)j 1s2 ,j2s2 ,j2p3 C)j 1s2 ,j2s2 ,j2p4 D)j 1s2 ,j2s2 ,j2p5
3. What jisjthejground-statejelectronicjconfigurationjof jajmagnesiumjcationj(Mg2+)?
A) 1s2 ,j2s2 ,j2p6 C) 1s2 ,j2s2 ,j2p6 ,j3s2
B) 1s2 ,j2s2 ,j2p6 ,j3s1 D) 1s2 ,j2s2 ,j2p6 ,j3s2 ,j3p2
4. What jisjthejground-statejelectronicjconfigurationjof jajchlorinejanionj(Cl—)?
A) 1s2 ,j2s2 ,j2p6 C) 1s2 ,j2s2 ,j2p6 ,j3s2 ,j3p5
B) 1s2 ,j2s2 ,j2p6 ,j3s2 ,j3p6 D) 1s2 ,j2s2 ,j2p6 ,j3s2 ,j3p4
5. Whichjof jthejfollowingjstatementsjabout jvalencejelectronsjisjtrue?
A) Theyjarejthejmost jtightlyjheld jelectrons.
B) Theyjdojnot jparticipatejinjchemicaljreactions.
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C) Theyjarejthejoutermost jelectrons.
D) Theyjrevealjthejperiod jnumberjof jajsecond-row jelement.
6. Whichjof jthejfollowingjstatementsjabout jbondingjisjtrue?
A) Covalent jbondsjresult jfromjthejtransferjof jelectronsjfromjonejelement jtojanother.
B) Ionicjbondsjresult jfromjthejtransferjof jelectronsjfromjajmetaljtojajnon-metal.
C) Ionicjbondsjresult jfromjthejsharingjof jelectronsjbetweenjtwojnon-metals.
D) Covalent jbondsjresult jfromjthejsharingjof jelectronsjbetweenjtwojmetals.
7. Whichjof jthejfollowingjwould jyoujexpect jtojhavejionicjbonds?
A) CO B)j FBr C)j NF3 D)j NaCl
8. Whichjof jthejfollowingjmoleculesjhasjnonpolarjcovalent jbonds?
A) HCl B)j N2 C)j CHCl3 D)j NO
9. Whichjof jthejfollowingjmoleculesjcontainjbothjcovalent jand jionicjbonds?
A) I,jII B)j I,jIV C)j II,jIII D)j II,jIV
10. Arrangejthejfollowingjbondsjinjdecreasingjorderjofjionicjcharacter,jputtingjthejmost jioni
cjfirst.
A) I j>jII j>jIII j>jIV C) IV j>jIII j>jII j>jI
B) IVj>jII j>jI j>jIII D) IV j>jII j>jIII j>jI
11. Whichjof jthejfollowingjstatementsjcorrectlyjdescribesjthejtypicaljnumberjof jbondsjforjcar
bon,jnitrogen,jand joxygenjinjmost jneutraljorganicjmolecules?
A) Carbonjformsj4jcovalent jbonds,jnitrogenjformsj2jcovalent jbondsjandjoxygenjformsj3jco
valent jbonds.
B) Carbonjformsj4jcovalent jbonds,jnitrogenjformsj3jcovalent jbondsjandjoxygenjformsj2jco
valent jbonds.
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C) Carbonjformsj4jcovalent jbonds,jnitrogenjformsj5jcovalent jbondsjandjoxygenjformsj2jco
valent jbonds.
D) Carbonjformsj4jcovalent jbonds,jnitrogenjformsj5jcovalent jbondsjandjoxygenjformsj4jco
valent jbonds.
12. Whichjisjnot janjacceptablejLewisjstructurejforjthejanionjCH 2 NCO —?
A) I B)j II C)j III D)j IV
13. Whichjof jthejfollowingjLewisjstructuresjisjcorrect?
A) I B)j II C)j III D)j IV
14. Whichjof jthejfollowingjLewisjstructuresjisjcorrect?
A) I,jII B)j I,jIII C)j II,jIII D)j III,jIV
15. Whichjisjthejcorrect jLewisjstructurejforjaceticjacid j(CH 3 CO 2 H)?
A) I B)j II C)j III D)j IV
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16. Injwhichjof jthejfollowingjionsjdoesjcarbonjhavejajformaljcharge?
A) I B)j II C)j III D)j Nonejof jthejabove
17. Injwhichjof jthejfollowingjionsjdoesjcarbonjhavejajformaljcharge?
A) I B)j II C)j III D)j Nonejof jthejabove
18. What jisjthejformaljchargejof jcarbonjinjcarbonjmonoxidej(CO)jwhenjdrawnjwithjajtriplejbond
?
A) 0 B)j -2 C)j -1 D)j +1
19. Whichjof jthejfollowingjstatementsjabout jconstitutionaljisomersjisjtrue?
A) Constitutionaljisomersjarejdifferent jmoleculesjhavingjdifferent jmolecularjformula.
B) Constitutionaljisomersjarejdifferent jmoleculesjhavingjsamejmolecularjformula.
C) Constitutionaljisomersjarejsamejmoleculesjhavingjdifferent jmolecularjformula.
D) Constitutionaljisomersjarejsamejmoleculesjhavingjthejsamejmolecularjformula.
20. How jmanyjconstitutionaljisomersjarejtherejforjajmoleculejhavingjthejmolecularjformulajC2
H 6 O?
A) 1 B)j 2 C)j 3 D)j 4
21. How jmanyjconstitutionaljisomersjarejtherejforjajmoleculejhavingjthejmolecularjC3 H8 O?
A) 1 B)j 2 C)j 3 D)j 4
22. How jmanyjconstitutionaljisomersjarejtherejforjajmoleculejhavingjthejmolecularjformulajC3
H6?
A) 1 B)j 2 C)j 3 D)j 4
23. How jmanyjconstitutionaljisomersjarejtherejforjajmoleculejhavingjthejmolecularjformulajC2
H 4 Cl2 ?
A) 1 B)j 2 C)j 3 D)j 4
24. How jmanyjdifferent jisomersjarejtherejforjajcompound jhavingjthejmolecularjformulajC3
H 6 O?
A) 4 B)j 5 C)j 6 D)j 7
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